Read the following statements. Which ones are correct? Be sure to explain how you know. I. BF3 and PF5 are examples of exceptions to the octet rule. II. BF4¯ and BF3-NH3 are examples of violations of the octet rule. III. Expanded valence shells occur most often when the central atom is bonded to a small, electronegative element. IV. The central atoms most capable of having expanded valence shells come from rows 3, 4, and 5 of the periodic table.

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**Title: Understanding Exceptions to the Octet Rule**

**Text:**

Read the following statements. Which ones are correct? Be sure to explain how you know.

I. BF₃ and PF₅ are examples of exceptions to the octet rule.

II. BF₄⁻ and BF₃-NH₃ are examples of violations of the octet rule.

III. Expanded valence shells occur most often when the central atom is bonded to a small, electronegative element.

IV. The central atoms most capable of having expanded valence shells come from rows 3, 4, and 5 of the periodic table. 

**Explanation:**

- **BF₃ and PF₅** are molecules that do not follow the octet rule. BF₃ is an electron-deficient molecule, and PF₅ has an expanded valence shell with 10 electrons.

- **BF₄⁻ and BF₃-NH₃** illustrate cases where the octet rule is modified or expanded. BF₄⁻ has a complete octet, and BF₃ forms an adduct with NH₃ by accepting a lone pair.

- **Expanded valence shells** are typical for central atoms bonded to elements with high electronegativity, due to the ability to accommodate extra electrons.

- **Central atoms in rows 3, 4, and 5** of the periodic table often have available d orbitals, allowing for expanded shell configurations. Examples include elements like phosphorus and sulfur.
Transcribed Image Text:**Title: Understanding Exceptions to the Octet Rule** **Text:** Read the following statements. Which ones are correct? Be sure to explain how you know. I. BF₃ and PF₅ are examples of exceptions to the octet rule. II. BF₄⁻ and BF₃-NH₃ are examples of violations of the octet rule. III. Expanded valence shells occur most often when the central atom is bonded to a small, electronegative element. IV. The central atoms most capable of having expanded valence shells come from rows 3, 4, and 5 of the periodic table. **Explanation:** - **BF₃ and PF₅** are molecules that do not follow the octet rule. BF₃ is an electron-deficient molecule, and PF₅ has an expanded valence shell with 10 electrons. - **BF₄⁻ and BF₃-NH₃** illustrate cases where the octet rule is modified or expanded. BF₄⁻ has a complete octet, and BF₃ forms an adduct with NH₃ by accepting a lone pair. - **Expanded valence shells** are typical for central atoms bonded to elements with high electronegativity, due to the ability to accommodate extra electrons. - **Central atoms in rows 3, 4, and 5** of the periodic table often have available d orbitals, allowing for expanded shell configurations. Examples include elements like phosphorus and sulfur.
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