Reaction of this bicycloalkene with bromine in carbon tetrachloride gives a trans dibro- mide. In both (a) and (b), the bromine atoms are trans to each other. However, only one of these products is formed. CH3 CH3 CH3 Br Br CH,Cl, + Br2 or Br Br (a) (b) Which trans dibromide is formed? How do you account for the fact that it is formed to the exclusion of the other trans dibromide?

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Reaction of this bicycloalkene with bromine in carbon tetrachloride gives a trans dibro-
mide. In both (a) and (b), the bromine atoms are trans to each other. However, only one
of these products is formed.
CH3
CH3
CH3
Br
Br
CH,Cl,
+ Br2
or
Br
Br
(a)
(b)
Which trans dibromide is formed? How do you account for the fact that it is formed to the
exclusion of the other trans dibromide?
Transcribed Image Text:Reaction of this bicycloalkene with bromine in carbon tetrachloride gives a trans dibro- mide. In both (a) and (b), the bromine atoms are trans to each other. However, only one of these products is formed. CH3 CH3 CH3 Br Br CH,Cl, + Br2 or Br Br (a) (b) Which trans dibromide is formed? How do you account for the fact that it is formed to the exclusion of the other trans dibromide?
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