[RCOOH], M [R’OH], M (HA], M Initial Rate, M-min¨ 0.35 0.35 0.50 4.60 0.62 0.35 0.50 8.14 0.35 0.81 0.50 10.6 0.35 0.50 0.75 9.84 Rate = k[RCOOH][R'OH] Rate = k[RCOOH][R'OH][HA] %3D Rate = k[RCOOR']/{[RCOOH][R'OH]} Rate = k[R'OH] Rate = k[RCOOH] %3D

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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[RCOOH], M
[R’OH], M
[HA], M
Initial Rate, M•min¨
23.
0.35
0.35
0.50
4.60
0.62
0.35
0.50
8.14
0.35
0.81
0.50
10.6
0.35
0.50
0.75
9,84
Rate = k[RCOOH][R'OH]
%3D
Rate = k[RCOOH][R'OH][HA]
Rate = k[RCOOR']/{[RCOOH][R'OH]}
%3D
Rate = k[R'OH]
Rate = k[RCOOH]
%D
Identify the rate-determining step based on the rate law you found
in question 23.
25.
0–H
ki
R-
С-0—Н
+ HA
R-¢+
A-
k2
0–H
Group 1
0–H
0–H
k3
R-C+
A-
R
-0–H
R—C—0—Н
k4
О—Н
R-ó+
A-
Group 2
H
0–H
R—С—0—н
k5
R+C-0–R'
+ H2O
+ HA
R-ó+
A-
Group 3
H.
Step 2 or Step 3
Step 1 or Step 2
Step 1 or Step 3
Step 2
Step 1
O Oo O O
Transcribed Image Text:[RCOOH], M [R’OH], M [HA], M Initial Rate, M•min¨ 23. 0.35 0.35 0.50 4.60 0.62 0.35 0.50 8.14 0.35 0.81 0.50 10.6 0.35 0.50 0.75 9,84 Rate = k[RCOOH][R'OH] %3D Rate = k[RCOOH][R'OH][HA] Rate = k[RCOOR']/{[RCOOH][R'OH]} %3D Rate = k[R'OH] Rate = k[RCOOH] %D Identify the rate-determining step based on the rate law you found in question 23. 25. 0–H ki R- С-0—Н + HA R-¢+ A- k2 0–H Group 1 0–H 0–H k3 R-C+ A- R -0–H R—C—0—Н k4 О—Н R-ó+ A- Group 2 H 0–H R—С—0—н k5 R+C-0–R' + H2O + HA R-ó+ A- Group 3 H. Step 2 or Step 3 Step 1 or Step 2 Step 1 or Step 3 Step 2 Step 1 O Oo O O
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