Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Title: Ranking Carbocations by Stability**
**Description:**
In this exercise, you will rank the following carbocations from most stable to least stable. The stability of a carbocation is an important factor in determining the reactivity and the outcome of many organic reactions.
**Carbocations:**
- **Carbocation A:** A simple methyl carbocation with no alkyl groups attached.
- **Carbocation B:** A secondary carbocation with one methyl group attached to the positively charged carbon atom.
- **Carbocation C:** A tertiary carbocation with two methyl groups attached to the positively charged carbon atom.
**Task:**
Rank the carbocations from most stable to least stable based on their structural features.
**Options:**
- ○ A > C > B
- ○ C > A > B
- ○ A > B > C
- ○ B > C > A
- ○ B > A > C
- ○ C > B > A
**Explanation:**
Consider the inductive and hyperconjugation effects of the alkyl groups. Tertiary carbocations are generally more stable than secondary, which are more stable than primary, due to electron-donating effects and greater hyperconjugation offered by alkyl groups.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F83ec917b-3e82-4dc1-b5e7-24fa4bff0896%2F592edf1a-356c-4b14-a706-d1cf35ba10f7%2Fsfeli8_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Ranking Carbocations by Stability**
**Description:**
In this exercise, you will rank the following carbocations from most stable to least stable. The stability of a carbocation is an important factor in determining the reactivity and the outcome of many organic reactions.
**Carbocations:**
- **Carbocation A:** A simple methyl carbocation with no alkyl groups attached.
- **Carbocation B:** A secondary carbocation with one methyl group attached to the positively charged carbon atom.
- **Carbocation C:** A tertiary carbocation with two methyl groups attached to the positively charged carbon atom.
**Task:**
Rank the carbocations from most stable to least stable based on their structural features.
**Options:**
- ○ A > C > B
- ○ C > A > B
- ○ A > B > C
- ○ B > C > A
- ○ B > A > C
- ○ C > B > A
**Explanation:**
Consider the inductive and hyperconjugation effects of the alkyl groups. Tertiary carbocations are generally more stable than secondary, which are more stable than primary, due to electron-donating effects and greater hyperconjugation offered by alkyl groups.
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