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Rank the basicity of the following compounds from weakest to strongest: a. CF3COO, C(F)H₂CH₂O. CF3CH₂CO™, NH₂™ b. CH3CH₂O, CH3CH2, CH3CH3, HC=C- C. CH3NH-, CH3C2S¯, (CH3)3CO™. CH3CH₂O-

Rank the basicity of the following compounds from weakest to strongest: a. CF3COO, C(F)H₂CH₂O. CF3CH₂CO™, NH₂™ b. CH3CH₂O, CH3CH2, CH3CH3, HC=C- C. CH3NH-, CH3C2S¯, (CH3)3CO™. CH3CH₂O-

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Ranking the Basicity of Compounds **Objective:** Rank the basicity of the following compounds from weakest to strongest: #### Group a: - CF₃COO⁻ - C(F)H₂CH₂O⁻ - CF₃CH₂CO⁻ - NH₂⁻ #### Group b: - CH₃CH₂O⁻ - CH₃CH₂⁻ - CH₃CH₃ - HC≡C⁻ #### Group c: - CH₃NH⁻ - CH₃C₂S⁻ - (CH₃)₃CO⁻ - CH₃CH₂O⁻ **Explanation:** To determine the order of basicity, it is essential to consider the stability of the conjugate base, the electron-withdrawing or electron-donating effects of substituents, and the hybridization of the atom bearing the negative charge. Generally, less stable conjugate bases correspond to stronger bases.
Transcribed Image Text:### Ranking the Basicity of Compounds **Objective:** Rank the basicity of the following compounds from weakest to strongest: #### Group a: - CF₃COO⁻ - C(F)H₂CH₂O⁻ - CF₃CH₂CO⁻ - NH₂⁻ #### Group b: - CH₃CH₂O⁻ - CH₃CH₂⁻ - CH₃CH₃ - HC≡C⁻ #### Group c: - CH₃NH⁻ - CH₃C₂S⁻ - (CH₃)₃CO⁻ - CH₃CH₂O⁻ **Explanation:** To determine the order of basicity, it is essential to consider the stability of the conjugate base, the electron-withdrawing or electron-donating effects of substituents, and the hybridization of the atom bearing the negative charge. Generally, less stable conjugate bases correspond to stronger bases.
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