r30. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride. 33. For whic products pressure (CH3);COH(aq) + H*(aq) + Cl(aq) → (CH3);CCI(aq) + H2O(1) (A)N2 (B) TiC For this reaction, Rate = k[(CH3)3COH][H*]. With which mechanism is this rate law consistent? (C) 2 0 (D) 4H • (A) (CH3);COH(aq) + H*(aq) = (CH3);C(OH2) (aq) fast 34, Chromi the mol (CH3)3E(OH1)*(aq)+ Cl(aq) → (CH3)3CCI(aq) + H2O(I) slow maintai (A) 1. (B) (CH3)3СОН(ад) + H'(аq) — (CH3);C(OH2)*(aq) fast (C) 3. slow A35. At 400 (CH3);C(OH2)*(ag) → (CH3);C*(aq) H20(1) (CH3)3C*(aq) + CI(aq) → (CH3);CCl(aq) fast (C) (CH3)3COH(aq) + Cl (aq) → (CH;);CCI(aq) + ОН (ад) What i slow ОН (аq) + H"(aд) — Н:0() fast (АУ 6 (D) (CH3)3COH(aq)→ (CH3)3C*(aq) + OH (aq) slow (C) 1 (CH3);C*(aq) + CI(aq) → (CH3);CCI(aq) fast Bos. 36. An un OH (aq)+ H*(aq)→ H2O(/) fast mixed A. Na(RO dissol 31. The diagrams below represent the progress of a reaction of A → B, with molecules of A represented by solid circles and molecules of B represented by open circles. Which statement best describes the reaction at t= 1000 s? NaOH added 4. fo hydrochloric acid 33. For which of the following reactions would the yield of products at equilibrium NOT increase at a higher pressure? CH(aq) → (1) (A) N2(g) + O2(g) = 2 NO(g) (B) Ti(s) + 2 Cl2(g) = TiCl4(g) ][H*]. With which (C) 2 C2H4(g) + 2 H2O(g) = 2 C2H6(g) + O2(g) (D) 4 HC(g) + O2(g) 2 H20(1) + 2 Cl2(g) fast 34,/ Chromium(III) hydroxide has Ksp = 1.6 x 10-30, What is the molar solubility of Cr(OH)3 in a solution whose pH is maintained at 6.00? D. slow (A) 1.6 x 10-12 mol L-1 (B) 1.6 x 10-8 mol L- fast (C) 3.6 x 10-8 mol L- (D) 1.6 x 10-6 mol L-1 slow A35. At 400 K, this reaction has K, = 8.2 x 10-4. %3D + (b. SO3(g) S02(g) +2 O2(g) CCI(aq) fast -);CCI(aq) slow What is Kp at 400 K for the following reaction? 2 SO3(g) = 2 SO2(g) + O2(g) fast (A) 6.7 x 10-7 (B) 8.2 x 104 OH (aq) slow (C) 1.6 × 10-3 (D) 2.9 x 10-2 CC(aq) fast Baa 36. An unknown monoprotic carboxylic acid RCOOH is mixed in a 1:1 mole ratio with its sodium salt, Na(RCOO). A 1.000 g sample of this 1:1 mixture is dissolved in 50 mL water and titrated with 0.5000 M fast ess of a reaction ted by solid y open circles. on at t= 1000 s? NaOH solution. The pH is measured as a function of added titrant to give the following titration curve: 13 12 11 pH 7. t= 1000 s e the ger changing. 4 cause not all of 3 10 6. with 16 (C) 1.50 5. Barium chlorio the following equ BaCl2(aq) + Na A student r (M = 20 11 10 8. 7. 8.
r30. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride. 33. For whic products pressure (CH3);COH(aq) + H*(aq) + Cl(aq) → (CH3);CCI(aq) + H2O(1) (A)N2 (B) TiC For this reaction, Rate = k[(CH3)3COH][H*]. With which mechanism is this rate law consistent? (C) 2 0 (D) 4H • (A) (CH3);COH(aq) + H*(aq) = (CH3);C(OH2) (aq) fast 34, Chromi the mol (CH3)3E(OH1)*(aq)+ Cl(aq) → (CH3)3CCI(aq) + H2O(I) slow maintai (A) 1. (B) (CH3)3СОН(ад) + H'(аq) — (CH3);C(OH2)*(aq) fast (C) 3. slow A35. At 400 (CH3);C(OH2)*(ag) → (CH3);C*(aq) H20(1) (CH3)3C*(aq) + CI(aq) → (CH3);CCl(aq) fast (C) (CH3)3COH(aq) + Cl (aq) → (CH;);CCI(aq) + ОН (ад) What i slow ОН (аq) + H"(aд) — Н:0() fast (АУ 6 (D) (CH3)3COH(aq)→ (CH3)3C*(aq) + OH (aq) slow (C) 1 (CH3);C*(aq) + CI(aq) → (CH3);CCI(aq) fast Bos. 36. An un OH (aq)+ H*(aq)→ H2O(/) fast mixed A. Na(RO dissol 31. The diagrams below represent the progress of a reaction of A → B, with molecules of A represented by solid circles and molecules of B represented by open circles. Which statement best describes the reaction at t= 1000 s? NaOH added 4. fo hydrochloric acid 33. For which of the following reactions would the yield of products at equilibrium NOT increase at a higher pressure? CH(aq) → (1) (A) N2(g) + O2(g) = 2 NO(g) (B) Ti(s) + 2 Cl2(g) = TiCl4(g) ][H*]. With which (C) 2 C2H4(g) + 2 H2O(g) = 2 C2H6(g) + O2(g) (D) 4 HC(g) + O2(g) 2 H20(1) + 2 Cl2(g) fast 34,/ Chromium(III) hydroxide has Ksp = 1.6 x 10-30, What is the molar solubility of Cr(OH)3 in a solution whose pH is maintained at 6.00? D. slow (A) 1.6 x 10-12 mol L-1 (B) 1.6 x 10-8 mol L- fast (C) 3.6 x 10-8 mol L- (D) 1.6 x 10-6 mol L-1 slow A35. At 400 K, this reaction has K, = 8.2 x 10-4. %3D + (b. SO3(g) S02(g) +2 O2(g) CCI(aq) fast -);CCI(aq) slow What is Kp at 400 K for the following reaction? 2 SO3(g) = 2 SO2(g) + O2(g) fast (A) 6.7 x 10-7 (B) 8.2 x 104 OH (aq) slow (C) 1.6 × 10-3 (D) 2.9 x 10-2 CC(aq) fast Baa 36. An unknown monoprotic carboxylic acid RCOOH is mixed in a 1:1 mole ratio with its sodium salt, Na(RCOO). A 1.000 g sample of this 1:1 mixture is dissolved in 50 mL water and titrated with 0.5000 M fast ess of a reaction ted by solid y open circles. on at t= 1000 s? NaOH solution. The pH is measured as a function of added titrant to give the following titration curve: 13 12 11 pH 7. t= 1000 s e the ger changing. 4 cause not all of 3 10 6. with 16 (C) 1.50 5. Barium chlorio the following equ BaCl2(aq) + Na A student r (M = 20 11 10 8. 7. 8.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Questions 30 and 34. The correct answers are in pink
![r30. Tert-butyl alcohol reacts with aqueous hydrochloric acid
to give tert-butyl chloride.
33. For whic
products
pressure
(CH3);COH(aq) + H*(aq) + Cl(aq) →
(CH3);CCI(aq) + H2O(1)
(A)N2
(B) TiC
For this reaction, Rate = k[(CH3)3COH][H*]. With which
mechanism is this rate law consistent?
(C) 2 0
(D) 4H
• (A) (CH3);COH(aq) + H*(aq) =
(CH3);C(OH2) (aq)
fast
34, Chromi
the mol
(CH3)3E(OH1)*(aq)+ Cl(aq) →
(CH3)3CCI(aq) + H2O(I)
slow
maintai
(A) 1.
(B) (CH3)3СОН(ад) + H'(аq) —
(CH3);C(OH2)*(aq)
fast
(C) 3.
slow A35. At 400
(CH3);C(OH2)*(ag) → (CH3);C*(aq)
H20(1)
(CH3)3C*(aq) + CI(aq) → (CH3);CCl(aq)
fast
(C) (CH3)3COH(aq) + Cl (aq) → (CH;);CCI(aq)
+ ОН (ад)
What i
slow
ОН (аq) + H"(aд) — Н:0()
fast
(АУ 6
(D) (CH3)3COH(aq)→ (CH3)3C*(aq) + OH (aq)
slow
(C) 1
(CH3);C*(aq) + CI(aq) → (CH3);CCI(aq)
fast
Bos.
36. An un
OH (aq)+ H*(aq)→ H2O(/)
fast
mixed
A.
Na(RO
dissol
31. The diagrams below represent the progress of a reaction
of A → B, with molecules of A represented by solid
circles and molecules of B represented by open circles.
Which statement best describes the reaction at t= 1000 s?
NaOH
added](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F82a08560-2714-41d6-a009-aad50ffff1b9%2F5952240a-5a37-489d-a589-44c9a19a25cb%2Fi3z3e8k.jpeg&w=3840&q=75)
Transcribed Image Text:r30. Tert-butyl alcohol reacts with aqueous hydrochloric acid
to give tert-butyl chloride.
33. For whic
products
pressure
(CH3);COH(aq) + H*(aq) + Cl(aq) →
(CH3);CCI(aq) + H2O(1)
(A)N2
(B) TiC
For this reaction, Rate = k[(CH3)3COH][H*]. With which
mechanism is this rate law consistent?
(C) 2 0
(D) 4H
• (A) (CH3);COH(aq) + H*(aq) =
(CH3);C(OH2) (aq)
fast
34, Chromi
the mol
(CH3)3E(OH1)*(aq)+ Cl(aq) →
(CH3)3CCI(aq) + H2O(I)
slow
maintai
(A) 1.
(B) (CH3)3СОН(ад) + H'(аq) —
(CH3);C(OH2)*(aq)
fast
(C) 3.
slow A35. At 400
(CH3);C(OH2)*(ag) → (CH3);C*(aq)
H20(1)
(CH3)3C*(aq) + CI(aq) → (CH3);CCl(aq)
fast
(C) (CH3)3COH(aq) + Cl (aq) → (CH;);CCI(aq)
+ ОН (ад)
What i
slow
ОН (аq) + H"(aд) — Н:0()
fast
(АУ 6
(D) (CH3)3COH(aq)→ (CH3)3C*(aq) + OH (aq)
slow
(C) 1
(CH3);C*(aq) + CI(aq) → (CH3);CCI(aq)
fast
Bos.
36. An un
OH (aq)+ H*(aq)→ H2O(/)
fast
mixed
A.
Na(RO
dissol
31. The diagrams below represent the progress of a reaction
of A → B, with molecules of A represented by solid
circles and molecules of B represented by open circles.
Which statement best describes the reaction at t= 1000 s?
NaOH
added
![4.
fo
hydrochloric acid
33. For which of the following reactions would the yield of
products at equilibrium NOT increase at a higher
pressure?
CH(aq) →
(1)
(A) N2(g) + O2(g) = 2 NO(g)
(B) Ti(s) + 2 Cl2(g) = TiCl4(g)
][H*]. With which
(C) 2 C2H4(g) + 2 H2O(g) = 2 C2H6(g) + O2(g)
(D) 4 HC(g) + O2(g) 2 H20(1) + 2 Cl2(g)
fast
34,/ Chromium(III) hydroxide has Ksp = 1.6 x 10-30, What is
the molar solubility of Cr(OH)3 in a solution whose pH is
maintained at 6.00?
D.
slow
(A) 1.6 x 10-12 mol L-1
(B) 1.6 x 10-8 mol L-
fast
(C) 3.6 x 10-8 mol L-
(D) 1.6 x 10-6 mol L-1
slow A35. At 400 K, this reaction has K, = 8.2 x 10-4.
%3D
+ (b.
SO3(g) S02(g) +2 O2(g)
CCI(aq)
fast
-);CCI(aq) slow
What is Kp at 400 K for the following reaction?
2 SO3(g) = 2 SO2(g) + O2(g)
fast
(A) 6.7 x 10-7
(B) 8.2 x 104
OH (aq) slow
(C) 1.6 × 10-3
(D) 2.9 x 10-2
CC(aq)
fast
Baa
36. An unknown monoprotic carboxylic acid RCOOH is
mixed in a 1:1 mole ratio with its sodium salt,
Na(RCOO). A 1.000 g sample of this 1:1 mixture is
dissolved in 50 mL water and titrated with 0.5000 M
fast
ess of a reaction
ted by solid
y open circles.
on at t= 1000 s?
NaOH solution. The pH is measured as a function of
added titrant to give the following titration curve:
13
12
11
pH
7.
t= 1000 s
e the
ger changing.
4
cause not all of
3
10
6.
with
16 (C) 1.50
5. Barium chlorio
the following equ
BaCl2(aq) + Na
A student r
(M = 20
11
10
8.
7.
8.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F82a08560-2714-41d6-a009-aad50ffff1b9%2F5952240a-5a37-489d-a589-44c9a19a25cb%2Frvh14g.jpeg&w=3840&q=75)
Transcribed Image Text:4.
fo
hydrochloric acid
33. For which of the following reactions would the yield of
products at equilibrium NOT increase at a higher
pressure?
CH(aq) →
(1)
(A) N2(g) + O2(g) = 2 NO(g)
(B) Ti(s) + 2 Cl2(g) = TiCl4(g)
][H*]. With which
(C) 2 C2H4(g) + 2 H2O(g) = 2 C2H6(g) + O2(g)
(D) 4 HC(g) + O2(g) 2 H20(1) + 2 Cl2(g)
fast
34,/ Chromium(III) hydroxide has Ksp = 1.6 x 10-30, What is
the molar solubility of Cr(OH)3 in a solution whose pH is
maintained at 6.00?
D.
slow
(A) 1.6 x 10-12 mol L-1
(B) 1.6 x 10-8 mol L-
fast
(C) 3.6 x 10-8 mol L-
(D) 1.6 x 10-6 mol L-1
slow A35. At 400 K, this reaction has K, = 8.2 x 10-4.
%3D
+ (b.
SO3(g) S02(g) +2 O2(g)
CCI(aq)
fast
-);CCI(aq) slow
What is Kp at 400 K for the following reaction?
2 SO3(g) = 2 SO2(g) + O2(g)
fast
(A) 6.7 x 10-7
(B) 8.2 x 104
OH (aq) slow
(C) 1.6 × 10-3
(D) 2.9 x 10-2
CC(aq)
fast
Baa
36. An unknown monoprotic carboxylic acid RCOOH is
mixed in a 1:1 mole ratio with its sodium salt,
Na(RCOO). A 1.000 g sample of this 1:1 mixture is
dissolved in 50 mL water and titrated with 0.5000 M
fast
ess of a reaction
ted by solid
y open circles.
on at t= 1000 s?
NaOH solution. The pH is measured as a function of
added titrant to give the following titration curve:
13
12
11
pH
7.
t= 1000 s
e the
ger changing.
4
cause not all of
3
10
6.
with
16 (C) 1.50
5. Barium chlorio
the following equ
BaCl2(aq) + Na
A student r
(M = 20
11
10
8.
7.
8.
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