Question (4a) Draw the generic equilibrium for an ATRP polymerization. Make sure to include all rate Constants. (b) Use this equilibrium to derive an equation for the rate of an ATRP polymerization. (c) While nitroxide mediated polymerization has been shown to be effective for the polymerization of styrene, it is less so for methacrylate monomers. State why that is, and draw the mechanism for any side-reactions that you use in your answer.

Question (4a) Draw the generic equilibrium for an ATRP polymerization. Make sure to include all rate Constants. (b) Use this equilibrium to derive an equation for the rate of an ATRP polymerization. (c) While nitroxide mediated polymerization has been shown to be effective for the polymerization of styrene, it is less so for methacrylate monomers. State why that is, and draw the mechanism for any side-reactions that you use in your answer.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

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