Question 4: Suppose that we want to think of energy as a function of temperature and volume, E(T,V). Show that the total differential dE may be written: dE = C,dT + Kr

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**Question 4:** Suppose that we want to think of energy as a function of temperature and volume, E(T, V). Show that the total differential dE may be written:

\[ dE = C_V dT + \left( T \frac{\alpha}{\kappa_T} - P \right) dV. \]

In this equation:

- \( C_V \) is the heat capacity at constant volume.
- \( \alpha \) is the coefficient of thermal expansion.
- \( \kappa_T \) is the isothermal compressibility.
- \( T \) represents temperature.
- \( P \) represents pressure.
- \( dT \) and \( dV \) are infinitesimal changes in temperature and volume, respectively. 

This expression demonstrates how changes in temperature and volume can affect the energy of a system.
Transcribed Image Text:**Question 4:** Suppose that we want to think of energy as a function of temperature and volume, E(T, V). Show that the total differential dE may be written: \[ dE = C_V dT + \left( T \frac{\alpha}{\kappa_T} - P \right) dV. \] In this equation: - \( C_V \) is the heat capacity at constant volume. - \( \alpha \) is the coefficient of thermal expansion. - \( \kappa_T \) is the isothermal compressibility. - \( T \) represents temperature. - \( P \) represents pressure. - \( dT \) and \( dV \) are infinitesimal changes in temperature and volume, respectively. This expression demonstrates how changes in temperature and volume can affect the energy of a system.
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