Question 4: Suppose that we want to think of energy as a function of temperature and volume, E(T,V). Show that the total differential dE may be written: dE = C,dT + Kr
Question 4: Suppose that we want to think of energy as a function of temperature and volume, E(T,V). Show that the total differential dE may be written: dE = C,dT + Kr
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![**Question 4:** Suppose that we want to think of energy as a function of temperature and volume, E(T, V). Show that the total differential dE may be written:
\[ dE = C_V dT + \left( T \frac{\alpha}{\kappa_T} - P \right) dV. \]
In this equation:
- \( C_V \) is the heat capacity at constant volume.
- \( \alpha \) is the coefficient of thermal expansion.
- \( \kappa_T \) is the isothermal compressibility.
- \( T \) represents temperature.
- \( P \) represents pressure.
- \( dT \) and \( dV \) are infinitesimal changes in temperature and volume, respectively.
This expression demonstrates how changes in temperature and volume can affect the energy of a system.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1c77a87f-aa74-4cd4-9405-77907f1db03b%2F9dc8a32f-5dea-42a8-80c5-2300a35f5f1f%2Fn6f8jav_processed.png&w=3840&q=75)
Transcribed Image Text:**Question 4:** Suppose that we want to think of energy as a function of temperature and volume, E(T, V). Show that the total differential dE may be written:
\[ dE = C_V dT + \left( T \frac{\alpha}{\kappa_T} - P \right) dV. \]
In this equation:
- \( C_V \) is the heat capacity at constant volume.
- \( \alpha \) is the coefficient of thermal expansion.
- \( \kappa_T \) is the isothermal compressibility.
- \( T \) represents temperature.
- \( P \) represents pressure.
- \( dT \) and \( dV \) are infinitesimal changes in temperature and volume, respectively.
This expression demonstrates how changes in temperature and volume can affect the energy of a system.
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