Question 2 A N2(1)/CO2(2) gaseous mixture which contains 0.04 mol of N2 and 0.04 mol of CO2 in a volume of 0.001 m' at a temperature of 25°C. The second virial coefficients at this temperature have the values a) B11 -4.8×10-6 m/mol B22 -124.5x106 m²/mol B12 -47.5x10-6 m³/mol

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Question 2
A N2(1)/CO2(2) gaseous mixture which contains 0.04 mol of N2 and 0.04 mol of
а)
CO2 in a volume of 0.001 m at a temperature of 25°C. The second virial coefficients at
this temperature have the values
B11
-4.8×10-6 m/mol
B22 -124.5×106 m²/mol
B12 -47.5x106 m²/mol
Compare the pressure (in Pa) of the real gas with ideal gas and give comment.
b)
The partial molar volume of benzene (1) in cyclohexane (2) at 30 °C is given by the
following expression:
V, = 92.6 – 5.28 x, + 2.64 xỉ
(cm/mol)
Find the partial molar volume of cyclohexane (V2) and total volume (V) at x1 = 0.3. Molar
volume of pure cyclohexane (V2) is 109.44 cm /mol.
N.B. Use Gibbs/Duhem equation at constant temperature and pressure.
Determine the standard boiling point of benzene and its molar enthalpy of
vaporization at 298.15K.
Transcribed Image Text:Question 2 A N2(1)/CO2(2) gaseous mixture which contains 0.04 mol of N2 and 0.04 mol of а) CO2 in a volume of 0.001 m at a temperature of 25°C. The second virial coefficients at this temperature have the values B11 -4.8×10-6 m/mol B22 -124.5×106 m²/mol B12 -47.5x106 m²/mol Compare the pressure (in Pa) of the real gas with ideal gas and give comment. b) The partial molar volume of benzene (1) in cyclohexane (2) at 30 °C is given by the following expression: V, = 92.6 – 5.28 x, + 2.64 xỉ (cm/mol) Find the partial molar volume of cyclohexane (V2) and total volume (V) at x1 = 0.3. Molar volume of pure cyclohexane (V2) is 109.44 cm /mol. N.B. Use Gibbs/Duhem equation at constant temperature and pressure. Determine the standard boiling point of benzene and its molar enthalpy of vaporization at 298.15K.
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