Question 14 What reagents are necessary to carry out the conversion shown? `NH2 `NH2 LIAIH4; H2O 1) SOCI; 2) xs NH, HO NH2 3) xs LAH 4) H;0 1) xs LAH 2) H20 SOch xs NH) NH2

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please provide a complete reaction mechanism (This includes arrow pushing mechanism, resonance stabilization, charges for instance). You can choose what question to answer. Correct answers for the final product and its reactants are provided. I hope I can receive a complete answer as much as possible. (Only choose 13, 14, and 15)

Question 12
What is the predicted product of the reaction shown?
Br
NH2
1. NaN3
2. Нz, Pd
Question 13
Provide a stepwise synthesis of 3-amino-2-methylpentane using the Gabriel synthesis.
1 КОН3; 2.
; 3. H3O*; 4. NaOH
54. Provide a stepwise synthesis of 3-amino-2-methylpentane using the Gabriel synthesis.
Ans:
Кон
NH
COH
H;O*
NH,
COH
Question 14
What reagents are necessary to carry out the conversion shown?
`NH2
`NH2
LIAIH4; H20
1) SOCI;
2) xs NH,
HO,
NH2
3) xs LAH
4) H20
1) xs LAH
2) H0
SOCh
xs NH3
NH2
8=o
Transcribed Image Text:Question 12 What is the predicted product of the reaction shown? Br NH2 1. NaN3 2. Нz, Pd Question 13 Provide a stepwise synthesis of 3-amino-2-methylpentane using the Gabriel synthesis. 1 КОН3; 2. ; 3. H3O*; 4. NaOH 54. Provide a stepwise synthesis of 3-amino-2-methylpentane using the Gabriel synthesis. Ans: Кон NH COH H;O* NH, COH Question 14 What reagents are necessary to carry out the conversion shown? `NH2 `NH2 LIAIH4; H20 1) SOCI; 2) xs NH, HO, NH2 3) xs LAH 4) H20 1) xs LAH 2) H0 SOCh xs NH3 NH2 8=o
Question 15
Propose an efficient synthesis for the following transformation:
The transformation above can be performed with some reagent or combination of the reagents listed below. Give the
necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there
is more than one correct solution, provide just one answer.
A
в
t-BUOK
HBr, ROOR
Na,Cr207, H2SO4.
H20
HBr
E
F
G
1) MeMgBr; 2)
H30*
H2, Lindlar's cat.
TSCI, py
dilute H2SO4
K
1) LIAIH4; 2)
H3O*
conc. H2SO4, heat
1) BH3-THF; 2) H2O2,
DMP or PCC
NaOH
IGA
1) LAH
2) H20
3) TSCI, py
4) t-BUOK
1) LAH
2) H20
он
OTs
t-BUOK
TSCI,
pyridine
Transcribed Image Text:Question 15 Propose an efficient synthesis for the following transformation: The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A в t-BUOK HBr, ROOR Na,Cr207, H2SO4. H20 HBr E F G 1) MeMgBr; 2) H30* H2, Lindlar's cat. TSCI, py dilute H2SO4 K 1) LIAIH4; 2) H3O* conc. H2SO4, heat 1) BH3-THF; 2) H2O2, DMP or PCC NaOH IGA 1) LAH 2) H20 3) TSCI, py 4) t-BUOK 1) LAH 2) H20 он OTs t-BUOK TSCI, pyridine
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