QUESTION 13 1,3-cyclohexadiene is aromatic Has lower heat of hydrogenation has higher heat of hydrogenation o Good dienophile QUESTION 14 Influencing nature of the substituent in the elctrophilic substitution of benzene is due to o 1. inductive effect 2. thermodynamic effect 3. resonance effect 4. Both 1 and 3 QUESTION 15 Ethanol is converted to chloro ethane using the following reagent and mechanism 1. SOCI2 / SN2 2. HCI / SN1 3. SOCI2/ SN1 4. HCI / SN2 QUESTION 16 A good protecting group should: 1. Should react with the reagents used to carry out the desired reaction O 2. It should be difficult to remove after the reaction is finished o 3. It should be stable throughout the reaction 4. Both 1 and 2 QUESTION 17

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Chapter1: Chemical Foundations
Section: Chapter Questions
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QUESTION 13
1,3-cyclohexadiene is
aromatic
Has lower heat of hydrogenation
has higher heat of hydrogenation
o Good dienophile
QUESTION 14
Influencing nature of the substituent in the elctrophilic substitution of benzene is due to
o 1. inductive effect
2. thermodynamic effect
3. resonance effect
4. Both 1 and 3
QUESTION 15
Ethanol is converted to chloro ethane using the following reagent and mechanism
1. SOCI2 / SN2
2. HCI / SN1
3. SOCI2/ SN1
4. HCI / SN2
QUESTION 16
A good protecting group should:
1. Should react with the reagents used to carry out the desired reaction
O 2. It should be difficult to remove after the reaction is finished
o 3. It should be stable throughout the reaction
4. Both 1 and 2
QUESTION 17
Wolf Kishner reaction is used to convert
1. carbonyl group to carbon carbon double bond
2. Carbonyl group to an alcohol
3. Carbonyl group to CH2 group
4. Ester group to aldehyde group
Transcribed Image Text:QUESTION 13 1,3-cyclohexadiene is aromatic Has lower heat of hydrogenation has higher heat of hydrogenation o Good dienophile QUESTION 14 Influencing nature of the substituent in the elctrophilic substitution of benzene is due to o 1. inductive effect 2. thermodynamic effect 3. resonance effect 4. Both 1 and 3 QUESTION 15 Ethanol is converted to chloro ethane using the following reagent and mechanism 1. SOCI2 / SN2 2. HCI / SN1 3. SOCI2/ SN1 4. HCI / SN2 QUESTION 16 A good protecting group should: 1. Should react with the reagents used to carry out the desired reaction O 2. It should be difficult to remove after the reaction is finished o 3. It should be stable throughout the reaction 4. Both 1 and 2 QUESTION 17 Wolf Kishner reaction is used to convert 1. carbonyl group to carbon carbon double bond 2. Carbonyl group to an alcohol 3. Carbonyl group to CH2 group 4. Ester group to aldehyde group
a. Which is a stronger acid? a or b?
NH2
NH3
a
b
b. If nitration is done on both of them, draw the structures of the products?
c. Identify a,b,c, and d
CH;CH2CHO
OzJZn/CH3COOH
b+ C
Ether
d.
Li(CH3)2Cu/H30*
T T T
Arial
A 5 (18p + T
Path: p
Words:0
QUESTION 12
a. How many different proton signals and carbon signals will be observed for the following compound in its proton
NMR spectrum? Indicate the proton spin multiplicity?
H3C
CH-O-C-CH2-CH
b. Predict the products of the reaction with acetaldehyde with the following reagents?
a. NABH4, then H30*
b. Dess_Martin reagent
c. Methylmagnesium bromide, then H30*
d. (C6H5)3P=CH2
Transcribed Image Text:a. Which is a stronger acid? a or b? NH2 NH3 a b b. If nitration is done on both of them, draw the structures of the products? c. Identify a,b,c, and d CH;CH2CHO OzJZn/CH3COOH b+ C Ether d. Li(CH3)2Cu/H30* T T T Arial A 5 (18p + T Path: p Words:0 QUESTION 12 a. How many different proton signals and carbon signals will be observed for the following compound in its proton NMR spectrum? Indicate the proton spin multiplicity? H3C CH-O-C-CH2-CH b. Predict the products of the reaction with acetaldehyde with the following reagents? a. NABH4, then H30* b. Dess_Martin reagent c. Methylmagnesium bromide, then H30* d. (C6H5)3P=CH2
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