Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice.butanoic acid, 2-bromobutanoic acid,3-bromobutanoic acid,4-bromobutanoic acidQ2:- : Define the following terms? Give examplea- dextrorotatoryb- meso compoundC- specific rotationQ3:- Draw and specify as R or S the enantiomers (if any) of:(a) 3-bromohexane(d) 1,3-dichloropentaneQ4:- Draw structures, give names, and classify as primary, secondary, or tertiary amine:the eight isomeric amines of formula CaH11NQ5:- Give structures and names of the principal organic reactants and products of the following reactions.a- conversion of Carboxylic Acids into Estersb- Hydrolysis of nitrites.c- Hofmann degradation of amidesQ6:- Arrange the compounds of each set in order of basicity ? Explain your choice.ethylamine,2-aminoethanol,3-amino-l-propanolQ7:- Which compound has the highest boiling point Acetic acid or Propan-1-ol ? Why ?Q8:- How can prepare Acetic acid by Industrial and lab methods ? compere between them ?Q9:- Outline a possible laboratory, synthesis of each of the following compounds from benzene and/ortoluene, using any needed aliphatic and inorganic reagents,(a) m-bromophenol(b) 5-bromo-2-methylphenolQ10:- Explain how Esters are more reactive than amides in nucleophilic acyl substitution reactions.with best wishProf. Dr. Nabeel A.

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Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice. butanoic acid, 2-bromobutanoic acid, 3-bromobutanoic acid, 4-bromobutanoic acid

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Q1:- Arrange the following compounds of each set in order of decreasing acidity ? Explain your choice.
butanoic acid, 2-bromobutanoic acid,
3-bromobutanoic acid,
4-bromobutanoic acid
Q2:- : Define the following terms? Give example
a- dextrorotatory
b- meso compound
C- specific rotation
Q3:- Draw and specify as R or S the enantiomers (if any) of:
(a) 3-bromohexane
(d) 1,3-dichloropentane
Q4:- Draw structures, give names, and classify as primary, secondary, or tertiary amine:
the eight isomeric amines of formula CaH11N
Q5:- Give structures and names of the principal organic reactants and products of the following reactions.
a- conversion of Carboxylic Acids into Esters
b- Hydrolysis of nitrites.
c- Hofmann degradation of amides
Q6:- Arrange the compounds of each set in order of basicity ? Explain your choice.
ethylamine,
2-aminoethanol,
3-amino-l-propanol
Q7:- Which compound has the highest boiling point Acetic acid or Propan-1-ol ? Why ?
Q8:- How can prepare Acetic acid by Industrial and lab methods ? compere between them ?
Q9:- Outline a possible laboratory, synthesis of each of the following compounds from benzene and/or
toluene, using any needed aliphatic and inorganic reagents,
(a) m-bromophenol
(b) 5-bromo-2-methylphenol
Q10:- Explain how Esters are more reactive than amides in nucleophilic acyl substitution reactions.
with best wish
Prof. Dr. Nabeel A.

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