Q.4 Consider a system consisting of 1.5 mol CO2(g), initially at 15°C and 9.0 atm and confined to a cylinder of cross-section 100.0 cm². The sample is allowed to expand adiabatically against an external pressure of 1.5 atm until the piston has moved outwards through 15 cm. Assume that carbon dioxide may be considered a perfect gas with Cy,m = 28.8 J K-1 mol, and calculate : q, w, AU, AT and AS.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Q.4
Consider a system consisting of 1.5 mol CO2(g), initially at 15°C and 9.0
atm and confined to a cylinder of cross-section 100.0 cm². The sample is allowed
to expand adiabatically against an external pressure of 1.5 atm until the piston has
moved outwards through 15 cm. Assume that carbon dioxide may be considered a
perfect gas
with Cv,m
= 28.8 J K-1 mol, and calculate : q, w, AU, AT and AS.
Transcribed Image Text:Q.4 Consider a system consisting of 1.5 mol CO2(g), initially at 15°C and 9.0 atm and confined to a cylinder of cross-section 100.0 cm². The sample is allowed to expand adiabatically against an external pressure of 1.5 atm until the piston has moved outwards through 15 cm. Assume that carbon dioxide may be considered a perfect gas with Cv,m = 28.8 J K-1 mol, and calculate : q, w, AU, AT and AS.
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