Purpose of Experiment: The purpose 6E the experiment is to provde an example of a reacthion of an organometallic feaetion heagent with an aldehude to prepare an aichol I. II. Reactions carried out: G3H3BZQNHI ÇI Hao, THẾ Br Ha 0,THF Zn, N tyCI znB-(WHs)a П. Data Isolated yield of product: Theoretical yield of adduct: Percent yield of adduct: IV. Questions 1. Normally, most organometallics are very sensitive to water and even trace amounts can prevent their formation. What is the predominant reaction of organometallics with water? (Write the general reaction beginning with R-Metal + H2O →) 2. Draw the structures of the product of the reaction of each of the organometallics below with water. a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 3. Draw the structures of the product of the reaction of each of the organometallics below with D20. a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 11

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Chapter1: Chemical Foundations
Section: Chapter Questions
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Question 1

Purpose of Experiment:
The purpose 6E the experiment is to provde an example
of a reacthion of an organometallic feaetion heagent with an
aldehude to prepare an aichol
I.
II.
Reactions carried out:
G3H3BZQNHI ÇI
Hao, THẾ
Br
Ha 0,THF
Zn, N tyCI
znB-(WHs)a
П.
Data
Isolated yield of product:
Theoretical yield of adduct:
Percent yield of adduct:
IV.
Questions
1. Normally, most organometallics are very sensitive to water and even trace amounts can prevent
their formation. What is the predominant reaction of organometallics with water? (Write the
general reaction beginning with R-Metal + H2O →)
2. Draw the structures of the product of the reaction of each of the organometallics below with
water.
a. butyllithium
b. phenylmagnesium bromide
c. lithium dicyclohexylcuprate(I)
3. Draw the structures of the product of the reaction of each of the organometallics below with
D20.
a. butyllithium
b. phenylmagnesium bromide
c. lithium dicyclohexylcuprate(I)
11
Transcribed Image Text:Purpose of Experiment: The purpose 6E the experiment is to provde an example of a reacthion of an organometallic feaetion heagent with an aldehude to prepare an aichol I. II. Reactions carried out: G3H3BZQNHI ÇI Hao, THẾ Br Ha 0,THF Zn, N tyCI znB-(WHs)a П. Data Isolated yield of product: Theoretical yield of adduct: Percent yield of adduct: IV. Questions 1. Normally, most organometallics are very sensitive to water and even trace amounts can prevent their formation. What is the predominant reaction of organometallics with water? (Write the general reaction beginning with R-Metal + H2O →) 2. Draw the structures of the product of the reaction of each of the organometallics below with water. a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 3. Draw the structures of the product of the reaction of each of the organometallics below with D20. a. butyllithium b. phenylmagnesium bromide c. lithium dicyclohexylcuprate(I) 11
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