Propose a mechanism, using curved arrows, for the base-catalysed aldol reaction and the subsequent dehydration between furfural and cyclohexanone Q6. КОН H
Propose a mechanism, using curved arrows, for the base-catalysed aldol reaction and the subsequent dehydration between furfural and cyclohexanone Q6. КОН H
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Solve Q 4,5,6 with expalanation

Transcribed Image Text:Q6.
Propose a mechanism, using curved arrows, for the base-catalysed aldol reaction
and the subsequent dehydration between furfural and cyclohexanone
КОН
H

Transcribed Image Text:Part 1 Predict which side of the equilibria, for the following two reactions, lies towards the
left or towards the right and briefly explain why. (Note: You will need to find the pka values
in water of the acid and the conjugate acid to begin to solve the problem).
Q4.
Part 2 Also, show the movement of electrons using curly arrows between the two reactants
of each of the reactions.
?
Reaction 1
H,NEt
H,NEt
H.
H3C
Ethylamine
H3C
:0:
: Он
Reaction 2
CH3
CH3
CH3
CH3
H3C
H3C
Acetone
Q5.
Treatment of a carboxylic acid with trifluoroacetic anhydride leads to an
unsymmetrical anhydride that rapidly reacts with an alcohol to give an ester.
F3C
CF3
trifluoroacetic anhydride
CH;CH,OH
H3C"
+ CF;CO,H
OH
H3C
CF3
H3C
OCH2CH3
Unsymmetrical anhydride 1
Ethyl ester 2
(a) Propose a mechanism, using curved arrows, for the formation of the unsymmetrical
anhydride 1.
(b) Propose a mechanism, using curved arrows, for the formation of the ethyl ester 2.
(c) Why is the unsymmetrical anhydride unusually reactive?
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