PROBLEM Because of their conjugation, azo dyes are highly colored compounds 16-45 and the major artificial color source for textiles and food. Azo dyes are produced by the reaction of aryl diazonium salts with a second aromatic compound. In the product, the aromatic rings are linked by a diazo bridge (-N=N-). From the reactants provided, propose a structure for each azo dye and draw the electron-pushing mechanism. (a) (b) (c) NaO3S OH .. NaO3S CO₂Na CI -NEN NaO3S CH3 OCH3 CL S0₂Na CH3 N=N CL -N=N Methyl Orange Allura Red Lithol Rubine BK
PROBLEM Because of their conjugation, azo dyes are highly colored compounds 16-45 and the major artificial color source for textiles and food. Azo dyes are produced by the reaction of aryl diazonium salts with a second aromatic compound. In the product, the aromatic rings are linked by a diazo bridge (-N=N-). From the reactants provided, propose a structure for each azo dye and draw the electron-pushing mechanism. (a) (b) (c) NaO3S OH .. NaO3S CO₂Na CI -NEN NaO3S CH3 OCH3 CL S0₂Na CH3 N=N CL -N=N Methyl Orange Allura Red Lithol Rubine BK
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:PROBLEM Because of their conjugation, azo dyes are highly colored compounds
16-45 and the major artificial color source for textiles and food. Azo dyes are
produced by the reaction of aryl diazonium salts with a second aromatic
compound. In the product, the aromatic rings are linked by a diazo bridge
(-N=N-). From the reactants provided, propose a structure for each azo
dye and draw the electron-pushing mechanism.
(a)
(b)
(c)
NaO3S
OH
NaO3S
CO₂Na
OH
NaO3S
CH3
EN
SO3 Na
OCH3 CL
CH3
-> Methyl Orange
N=N
CI
NEN
Allura Red
Lithol Rubine BK
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