PROBLEM 4: Calculate the dew temperature for the following system at 1 atm and the corresponding composition of the liquid phase at equilibrium. Use a tolerance value of 1 x 10-3. Component propane wt % 0.40 cyclobutane pentane 0.50 0.06 octane 0.04 Name Formula CAS TABLE 2-8 Vapor Pressure of Inorganic and Organic Liquids, In P = C₁ + C₂/T + C₂ln T + C₁Tc5, P in Pa, T in K (Continued) Cmpd. no.* C5 C₁ C₂ C3 С4 Tmin K Pat Tmin Tmaxs K Pat Tmax 44835 61 p-Cresol CHO 106-44-5 118.53 -11,957 -13.293 8.70E-18 62 Cumene C9H12 98-82-8 102.81 63 Cyanogen C2N2 460-19-5 -8674.6 39.0596 -3473.98 -11.922 7.0048E-06 -2.48683 2.86E-17 629 307.93 177.14 245.25 3.45E+01 4.71E-04 7.44E+04 704.65 5.151E+06 631 3.226E+06 400.15 5.924E+06 64 Cyclobutane C₁HS 287-23-0 85.899 4884.4 65 Cyclohexane C6H12 110-82-7 51.087 -5226.4 -10.883 -4.2278 0.014934 1 182.48 1.80E+02 459.93 4.991E+06 9.76E-18 6 279.69 5.36E+03 553.8 4.093E+06 262 1-Nonyne C9H16 3452-09-3 114.77 263 Octadecane C18H38 593-45-3 157.68 -9430.8 -16,093 -13.631 8.1918E-06 -18.954 5.9272E-06 264 Octanal C8H160 124-13-0 74.0298 -8302.12 -7.19776 5.31E-18 265 Octane C8H18 111-65-9 96.084 -7900.2 -11.003 7.1802E-06 266 Octanoic acid C8H1602 124-07-2 116.477 -13,300.4 -12.6746 3.98E-18 267 1-Octanol C8H180 111-87-5 144.11083 -13,667.15667 -16.82611 9.37E-18 226266 223.15 301.31 4.50E-01 3.39E-02 598.05 2.619E+06 747 1.255E+06 251.65 3.49E+00 638.9 2.960E+06 216.38 2.11E+00 568.7 2.467E+06 289.65 2.76E-01 694.26 2.779E+06 257.65 9.60E-02 652.3 2.781E+06 268 2-Octanol C8H180 123-96-6 185.828 -14,520.2 269 2-Octanone C8H160 111-13-7 63.775 -7711.3 -23.6236 -5.7359 1.08854E-05 2 241.55 3.79E-02 629.8 2.749E+06 3.09E-18 6 252.85 4.68E+00 632.7 2.647E+06 270 3-Octanone C8H160 106-68-3 72.382 -8054.8 -7.0002 5.83E-18 6 255.55 7.84E+00 627.7 2.705E+06 271 1-Octene C8H16 111-66-0 74.936 -7155.9 -7.5843 1.71E-17 6 171.45 2.98E-03 566.9 2.663E+06 272 Octyl mercaptan C8H18 111-88-6 78.368 -8855.4 -7.8202 5.66E-18 6 223.95 3.05E-02 667.3 2.523E+06 273 1-Octyne C8H14 629-05-0 64.612 -6802.5 -6.0261 1.10E-17 6 193.55 1.04E-01 574 2.880E+06 274 Oxalic acid C2H2O4 144-62-7 107.476 -12,833.4 -11.3837 1.34E-18 6 462.65 1.97E+04 828 8.203E+06 275 Oxygen 02 7782-44-7 51.245 -1200.2 -6.4361 0.028405 1 54.36 1.48E+02 154.58 5.021E+06 276 Ozone 03 10028-15-6 40.067 -2204.8 -2.9351 7.75E-16 6 80.15 7.35E-01 261 5.566E+06 277 Pentadecane C15H32 629-62-9 135.57 -13,478 -16.022 5.6136E-06 2 283.07 1.29E-01 708 1.474E+06 278 Pentanal C5H10O 110-62-3 28.3041 -4657.56 -0.732149 -8.31E-18 6 191.59 1.16E+00 566.1 3.845E+06 279 Pentane C5H12 109-66-0 280 Pentanoic acid C5H1002 109-52-4 281 1-Pentanol C5H120 71-41-0 78.741 93.2079 114.74801 -5420.3 -10,470.5 -8.8253 9.6171E-06 2 143.42 6.86E-02 469.7 3.364E+06 -9.61345 5.62E-18 6 239.15 3.97E-02 639.16 3.630E+06 -10,643.3 -12.85754 1.25E-17 6 195.56 5.47E-04 588.1 3.897E+06 282 2-Pentanol C5H12O 6032-29-7 283 2-Pentanone C5H10O 107-87-9 116.828 84.635 -10,453 -13.1768 1.07E-17 6 200 5.24E-03 561 3.699E+06 -7078.4 -9.3 6.2702E-06 2 196.29 7.52E-01 561.08 3.706E+06 284 3-Pentanone C5H10O 96-22-0 44.286 -5415.1 -3.0913 1.86E-18 6 234.18 7.34E+01 560.95 3.699E+06 285 1-Pentene C5H10 109-67-1 46.994 -4289.5 -3.7345 2.54E-17 6 108.02 3.71E-05 464.8 3.562E+06 286 2-Pentyl mercaptan C5H12S 2084-19-7 58.985 -6193.1 -5.2746 7.40E-18 6 160.75 287 Pentyl mercaptan C5H12S 110-66-7 67.309 -6880.8 -6.4449 1.01E-17 6 197.45 1.77E-03 2.01E-01 584.3 3.537E+06 598 3.473E+06 288 1-Pentyne C3H8 627-19-0 82.805 -5683.8 -9.4301 0.000010767 2 167.45 289 2-Pentyne C5H8 627-21-4 137.29 -7447.1 -19.01 0.021415 1 163.83 290 Phenanthrene C14H10 85-01-8 72.958 -10,943 -6.7902 1.09E-18 6 291 Phenol CHO 108-95-2 95.444 -10,113 -10.09 6.76E-18 292 Phenyl isocyanate C₂H NO 293 Phthalic anhydride C8H403 294 Propadiene C3H4 103-71-9 85-44-9 463-49-0 86.779 -8101.8 -9.5303 6.1367E-06 126.5 -12,551 -15.002 7.7521E-06 57.069 -3682.7 -5.5662 6.5133E-06 62226 372.38 314.06 243.15 2.40E+00 2.05E-01 2.93E+01 1.88E+02 4.33E+00 481.2 4.170E+06 519 869 4.020E+06 2.902E+06 694.25 6.058E+06 653 4.063E+06 404.15 7.90E+02 791 4.734E+06 295 Propane C3H8 74-98-6 59.078 -3492.6 -6.0669 296 1-Propanol C3H₂O 71-23-8 84.66416 -8307.24422 -8.57673 0.000010919 7.51E-18 2 136.87 85.47 1.82E+01 394 5.218E+06 297 2-Propanol C3H8O 67-63-0 110.717 -9040 -12.676 0.000005538 62 146.95 185.26 1.68E-04 4.27E-07 1.69E-02 369.83 4.213E+06 536.8 508.3 5.169E+06 4.771E+06
PROBLEM 4: Calculate the dew temperature for the following system at 1 atm and the corresponding composition of the liquid phase at equilibrium. Use a tolerance value of 1 x 10-3. Component propane wt % 0.40 cyclobutane pentane 0.50 0.06 octane 0.04 Name Formula CAS TABLE 2-8 Vapor Pressure of Inorganic and Organic Liquids, In P = C₁ + C₂/T + C₂ln T + C₁Tc5, P in Pa, T in K (Continued) Cmpd. no.* C5 C₁ C₂ C3 С4 Tmin K Pat Tmin Tmaxs K Pat Tmax 44835 61 p-Cresol CHO 106-44-5 118.53 -11,957 -13.293 8.70E-18 62 Cumene C9H12 98-82-8 102.81 63 Cyanogen C2N2 460-19-5 -8674.6 39.0596 -3473.98 -11.922 7.0048E-06 -2.48683 2.86E-17 629 307.93 177.14 245.25 3.45E+01 4.71E-04 7.44E+04 704.65 5.151E+06 631 3.226E+06 400.15 5.924E+06 64 Cyclobutane C₁HS 287-23-0 85.899 4884.4 65 Cyclohexane C6H12 110-82-7 51.087 -5226.4 -10.883 -4.2278 0.014934 1 182.48 1.80E+02 459.93 4.991E+06 9.76E-18 6 279.69 5.36E+03 553.8 4.093E+06 262 1-Nonyne C9H16 3452-09-3 114.77 263 Octadecane C18H38 593-45-3 157.68 -9430.8 -16,093 -13.631 8.1918E-06 -18.954 5.9272E-06 264 Octanal C8H160 124-13-0 74.0298 -8302.12 -7.19776 5.31E-18 265 Octane C8H18 111-65-9 96.084 -7900.2 -11.003 7.1802E-06 266 Octanoic acid C8H1602 124-07-2 116.477 -13,300.4 -12.6746 3.98E-18 267 1-Octanol C8H180 111-87-5 144.11083 -13,667.15667 -16.82611 9.37E-18 226266 223.15 301.31 4.50E-01 3.39E-02 598.05 2.619E+06 747 1.255E+06 251.65 3.49E+00 638.9 2.960E+06 216.38 2.11E+00 568.7 2.467E+06 289.65 2.76E-01 694.26 2.779E+06 257.65 9.60E-02 652.3 2.781E+06 268 2-Octanol C8H180 123-96-6 185.828 -14,520.2 269 2-Octanone C8H160 111-13-7 63.775 -7711.3 -23.6236 -5.7359 1.08854E-05 2 241.55 3.79E-02 629.8 2.749E+06 3.09E-18 6 252.85 4.68E+00 632.7 2.647E+06 270 3-Octanone C8H160 106-68-3 72.382 -8054.8 -7.0002 5.83E-18 6 255.55 7.84E+00 627.7 2.705E+06 271 1-Octene C8H16 111-66-0 74.936 -7155.9 -7.5843 1.71E-17 6 171.45 2.98E-03 566.9 2.663E+06 272 Octyl mercaptan C8H18 111-88-6 78.368 -8855.4 -7.8202 5.66E-18 6 223.95 3.05E-02 667.3 2.523E+06 273 1-Octyne C8H14 629-05-0 64.612 -6802.5 -6.0261 1.10E-17 6 193.55 1.04E-01 574 2.880E+06 274 Oxalic acid C2H2O4 144-62-7 107.476 -12,833.4 -11.3837 1.34E-18 6 462.65 1.97E+04 828 8.203E+06 275 Oxygen 02 7782-44-7 51.245 -1200.2 -6.4361 0.028405 1 54.36 1.48E+02 154.58 5.021E+06 276 Ozone 03 10028-15-6 40.067 -2204.8 -2.9351 7.75E-16 6 80.15 7.35E-01 261 5.566E+06 277 Pentadecane C15H32 629-62-9 135.57 -13,478 -16.022 5.6136E-06 2 283.07 1.29E-01 708 1.474E+06 278 Pentanal C5H10O 110-62-3 28.3041 -4657.56 -0.732149 -8.31E-18 6 191.59 1.16E+00 566.1 3.845E+06 279 Pentane C5H12 109-66-0 280 Pentanoic acid C5H1002 109-52-4 281 1-Pentanol C5H120 71-41-0 78.741 93.2079 114.74801 -5420.3 -10,470.5 -8.8253 9.6171E-06 2 143.42 6.86E-02 469.7 3.364E+06 -9.61345 5.62E-18 6 239.15 3.97E-02 639.16 3.630E+06 -10,643.3 -12.85754 1.25E-17 6 195.56 5.47E-04 588.1 3.897E+06 282 2-Pentanol C5H12O 6032-29-7 283 2-Pentanone C5H10O 107-87-9 116.828 84.635 -10,453 -13.1768 1.07E-17 6 200 5.24E-03 561 3.699E+06 -7078.4 -9.3 6.2702E-06 2 196.29 7.52E-01 561.08 3.706E+06 284 3-Pentanone C5H10O 96-22-0 44.286 -5415.1 -3.0913 1.86E-18 6 234.18 7.34E+01 560.95 3.699E+06 285 1-Pentene C5H10 109-67-1 46.994 -4289.5 -3.7345 2.54E-17 6 108.02 3.71E-05 464.8 3.562E+06 286 2-Pentyl mercaptan C5H12S 2084-19-7 58.985 -6193.1 -5.2746 7.40E-18 6 160.75 287 Pentyl mercaptan C5H12S 110-66-7 67.309 -6880.8 -6.4449 1.01E-17 6 197.45 1.77E-03 2.01E-01 584.3 3.537E+06 598 3.473E+06 288 1-Pentyne C3H8 627-19-0 82.805 -5683.8 -9.4301 0.000010767 2 167.45 289 2-Pentyne C5H8 627-21-4 137.29 -7447.1 -19.01 0.021415 1 163.83 290 Phenanthrene C14H10 85-01-8 72.958 -10,943 -6.7902 1.09E-18 6 291 Phenol CHO 108-95-2 95.444 -10,113 -10.09 6.76E-18 292 Phenyl isocyanate C₂H NO 293 Phthalic anhydride C8H403 294 Propadiene C3H4 103-71-9 85-44-9 463-49-0 86.779 -8101.8 -9.5303 6.1367E-06 126.5 -12,551 -15.002 7.7521E-06 57.069 -3682.7 -5.5662 6.5133E-06 62226 372.38 314.06 243.15 2.40E+00 2.05E-01 2.93E+01 1.88E+02 4.33E+00 481.2 4.170E+06 519 869 4.020E+06 2.902E+06 694.25 6.058E+06 653 4.063E+06 404.15 7.90E+02 791 4.734E+06 295 Propane C3H8 74-98-6 59.078 -3492.6 -6.0669 296 1-Propanol C3H₂O 71-23-8 84.66416 -8307.24422 -8.57673 0.000010919 7.51E-18 2 136.87 85.47 1.82E+01 394 5.218E+06 297 2-Propanol C3H8O 67-63-0 110.717 -9040 -12.676 0.000005538 62 146.95 185.26 1.68E-04 4.27E-07 1.69E-02 369.83 4.213E+06 536.8 508.3 5.169E+06 4.771E+06
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Question
Vapor-Liquid Equilibrium Problem: Calculate using Raoult's Law and using the values in the table for the DIPPR constants
Transcribed Image Text:PROBLEM 4:
Calculate the dew temperature for the following system at 1 atm and the corresponding
composition of the liquid phase at equilibrium. Use a tolerance value of 1 x 10-3.
Component
propane
wt %
0.40
cyclobutane
pentane
0.50
0.06
octane
0.04
Transcribed Image Text:Name
Formula
CAS
TABLE 2-8 Vapor Pressure of Inorganic and Organic Liquids, In P = C₁ + C₂/T + C₂ln T + C₁Tc5, P in Pa, T in K (Continued)
Cmpd. no.*
C5
C₁
C₂
C3
С4
Tmin
K
Pat Tmin
Tmaxs
K
Pat Tmax
44835
61
p-Cresol
CHO
106-44-5
118.53
-11,957
-13.293
8.70E-18
62
Cumene
C9H12
98-82-8
102.81
63
Cyanogen
C2N2
460-19-5
-8674.6
39.0596 -3473.98
-11.922
7.0048E-06
-2.48683
2.86E-17
629
307.93
177.14
245.25
3.45E+01
4.71E-04
7.44E+04
704.65
5.151E+06
631
3.226E+06
400.15
5.924E+06
64
Cyclobutane
C₁HS
287-23-0
85.899
4884.4
65
Cyclohexane
C6H12
110-82-7
51.087
-5226.4
-10.883
-4.2278
0.014934
1
182.48
1.80E+02
459.93
4.991E+06
9.76E-18
6
279.69
5.36E+03
553.8
4.093E+06
262
1-Nonyne
C9H16
3452-09-3
114.77
263
Octadecane
C18H38
593-45-3
157.68
-9430.8
-16,093
-13.631
8.1918E-06
-18.954
5.9272E-06
264
Octanal
C8H160
124-13-0
74.0298
-8302.12
-7.19776 5.31E-18
265
Octane
C8H18
111-65-9
96.084
-7900.2
-11.003
7.1802E-06
266
Octanoic acid
C8H1602
124-07-2
116.477
-13,300.4
-12.6746
3.98E-18
267
1-Octanol
C8H180
111-87-5
144.11083
-13,667.15667
-16.82611
9.37E-18
226266
223.15
301.31
4.50E-01
3.39E-02
598.05
2.619E+06
747
1.255E+06
251.65
3.49E+00
638.9
2.960E+06
216.38
2.11E+00
568.7
2.467E+06
289.65
2.76E-01
694.26
2.779E+06
257.65
9.60E-02
652.3
2.781E+06
268
2-Octanol
C8H180
123-96-6
185.828
-14,520.2
269
2-Octanone
C8H160
111-13-7
63.775
-7711.3
-23.6236
-5.7359
1.08854E-05
2
241.55
3.79E-02
629.8
2.749E+06
3.09E-18
6
252.85
4.68E+00
632.7
2.647E+06
270
3-Octanone
C8H160
106-68-3
72.382
-8054.8
-7.0002
5.83E-18
6
255.55
7.84E+00
627.7
2.705E+06
271
1-Octene
C8H16
111-66-0
74.936
-7155.9
-7.5843
1.71E-17
6
171.45
2.98E-03
566.9
2.663E+06
272
Octyl mercaptan
C8H18
111-88-6
78.368
-8855.4
-7.8202
5.66E-18
6
223.95
3.05E-02
667.3
2.523E+06
273
1-Octyne
C8H14
629-05-0
64.612
-6802.5
-6.0261
1.10E-17
6
193.55
1.04E-01
574
2.880E+06
274
Oxalic acid
C2H2O4
144-62-7
107.476
-12,833.4
-11.3837
1.34E-18
6
462.65
1.97E+04
828
8.203E+06
275
Oxygen
02
7782-44-7
51.245
-1200.2
-6.4361
0.028405
1
54.36
1.48E+02
154.58
5.021E+06
276
Ozone
03
10028-15-6
40.067
-2204.8
-2.9351
7.75E-16
6
80.15
7.35E-01
261
5.566E+06
277
Pentadecane
C15H32
629-62-9
135.57
-13,478
-16.022
5.6136E-06
2
283.07
1.29E-01
708
1.474E+06
278
Pentanal
C5H10O
110-62-3
28.3041
-4657.56
-0.732149 -8.31E-18
6
191.59
1.16E+00
566.1
3.845E+06
279
Pentane
C5H12
109-66-0
280
Pentanoic acid
C5H1002
109-52-4
281
1-Pentanol
C5H120
71-41-0
78.741
93.2079
114.74801
-5420.3
-10,470.5
-8.8253
9.6171E-06
2
143.42
6.86E-02
469.7
3.364E+06
-9.61345
5.62E-18
6
239.15
3.97E-02
639.16
3.630E+06
-10,643.3
-12.85754 1.25E-17
6
195.56
5.47E-04
588.1
3.897E+06
282
2-Pentanol
C5H12O
6032-29-7
283
2-Pentanone
C5H10O
107-87-9
116.828
84.635
-10,453
-13.1768
1.07E-17
6
200
5.24E-03
561
3.699E+06
-7078.4
-9.3
6.2702E-06
2
196.29
7.52E-01
561.08
3.706E+06
284
3-Pentanone
C5H10O
96-22-0
44.286
-5415.1
-3.0913
1.86E-18
6
234.18
7.34E+01
560.95
3.699E+06
285
1-Pentene
C5H10
109-67-1
46.994
-4289.5
-3.7345
2.54E-17
6
108.02
3.71E-05
464.8
3.562E+06
286
2-Pentyl mercaptan
C5H12S
2084-19-7
58.985
-6193.1
-5.2746
7.40E-18
6
160.75
287
Pentyl mercaptan
C5H12S
110-66-7
67.309
-6880.8
-6.4449
1.01E-17
6
197.45
1.77E-03
2.01E-01
584.3
3.537E+06
598
3.473E+06
288
1-Pentyne
C3H8
627-19-0
82.805
-5683.8
-9.4301
0.000010767
2
167.45
289
2-Pentyne
C5H8
627-21-4
137.29
-7447.1
-19.01
0.021415
1
163.83
290
Phenanthrene
C14H10
85-01-8
72.958
-10,943
-6.7902
1.09E-18
6
291
Phenol
CHO
108-95-2
95.444
-10,113
-10.09
6.76E-18
292
Phenyl isocyanate
C₂H NO
293
Phthalic anhydride
C8H403
294
Propadiene
C3H4
103-71-9
85-44-9
463-49-0
86.779
-8101.8
-9.5303
6.1367E-06
126.5
-12,551
-15.002
7.7521E-06
57.069
-3682.7
-5.5662
6.5133E-06
62226
372.38
314.06
243.15
2.40E+00
2.05E-01
2.93E+01
1.88E+02
4.33E+00
481.2
4.170E+06
519
869
4.020E+06
2.902E+06
694.25
6.058E+06
653
4.063E+06
404.15
7.90E+02
791
4.734E+06
295
Propane
C3H8
74-98-6
59.078
-3492.6
-6.0669
296
1-Propanol
C3H₂O
71-23-8
84.66416
-8307.24422
-8.57673
0.000010919
7.51E-18
2
136.87
85.47
1.82E+01
394
5.218E+06
297
2-Propanol
C3H8O
67-63-0
110.717
-9040
-12.676
0.000005538
62
146.95
185.26
1.68E-04
4.27E-07
1.69E-02
369.83
4.213E+06
536.8
508.3
5.169E+06
4.771E+06
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The