Problem 118 IR Spectrum (liquid film) 1698 4000 3000 2000 1600 1200 800 v (cm") 100 Mass Spectrum UV Spectrum 80 M*. 136 A max 277 nm (log10€ 4.2) solvent : methanol 92 107 22 20 C3HBO2 160 m/e 40 80 120 200 240 280 13C NMR Spectrum (100.0 MHz, CDCI, solution) DEPT CH сH снt solvent proton decoupled 200 160 120 80 40 O 8 (ppm) expansion 'H NMR Spectrum (400 MHz, CDCI, solution) 7.65 7.45 6.85 6.65 ppm TMS 10 8 7 6 4 3 2 8 (ppm) % of base peak

EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter93: Refractometry
Section: Chapter Questions
Problem 2P
Question
Predict structure
Problem 118
IR Spectrum
(liquid film)
1698
4000
3000
2000
1600
1200
800
V (cm')
100
Mass Spectrum
UV Spectrum
80
M+ 136
A max 277 nm (log10ɛ 4.2)
60
40
solvent : methanol
92 107
223
20
C3H2O2
120
m/e
40
80
160
200
240
280
13C NMR Spectrum
(100.0 MHz, CDCI, solution)
DEPT CH CH,t CH
solvent
proton decoupled
200
160
120
80
O 8 (ppm)
40
expansion
1H NMR Spectrum
(400 MHz, CDCI, solution)
7.65 7.45
6.85 6.65 ppm
TMS
10
8
7
6
5
4
3
2
1
8 (ppm)
07
% of base peak
Transcribed Image Text:Problem 118 IR Spectrum (liquid film) 1698 4000 3000 2000 1600 1200 800 V (cm') 100 Mass Spectrum UV Spectrum 80 M+ 136 A max 277 nm (log10ɛ 4.2) 60 40 solvent : methanol 92 107 223 20 C3H2O2 120 m/e 40 80 160 200 240 280 13C NMR Spectrum (100.0 MHz, CDCI, solution) DEPT CH CH,t CH solvent proton decoupled 200 160 120 80 O 8 (ppm) 40 expansion 1H NMR Spectrum (400 MHz, CDCI, solution) 7.65 7.45 6.85 6.65 ppm TMS 10 8 7 6 5 4 3 2 1 8 (ppm) 07 % of base peak
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