Problem # 1 At 25°C and atmospheric pressure the volume change of mixing of binary liquid mixtures of species 1 and 2 is given by the equation AV = x1 x2(45x1 + 25 x2) where AV is in cm³ mol-1. At these conditions, V₁ = 110 and V₂ = 90 cm³ mol-1. Determine the partial molar volumes V₁ and V₂ in a mixture containing 40 mol-% of species 1 at the given conditions.

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Problem # 1
At 25°C and atmospheric pressure the volume change of mixing of binary liquid mixtures of species
1 and 2 is given by the equation
AV = x1 x2(45x1 + 25 x2)
where AV is in cm³ mol-1. At these conditions, V₁ = 110 and V₂ = 90 cm³ mol-1.
Determine the partial molar volumes V₁ and V₂ in a mixture containing 40 mol-% of species 1 at
the given conditions.
Transcribed Image Text:Problem # 1 At 25°C and atmospheric pressure the volume change of mixing of binary liquid mixtures of species 1 and 2 is given by the equation AV = x1 x2(45x1 + 25 x2) where AV is in cm³ mol-1. At these conditions, V₁ = 110 and V₂ = 90 cm³ mol-1. Determine the partial molar volumes V₁ and V₂ in a mixture containing 40 mol-% of species 1 at the given conditions.
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