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Predict the product of the aldol reaction shown below: Ex P Q OH NaOH Heat R S OH

Predict the product of the aldol reaction shown below: Ex P Q OH NaOH Heat R S OH

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Aldol Reaction Analysis** **Question:** Predict the product of the aldol reaction shown below: - **Reactants:** - A ketone with a methyl group (acetone) - A cyclic ketone - **Reagents:** - Sodium hydroxide (NaOH) - Heat **Possible Products:** - **P:** A structure with a methyl ketone and an additional cyclohexane ring - **Q:** A structure with an alcohol group attached to the carbon adjacent to the carbonyl group and a cyclohexane ring - **R:** A structure featuring a methyl group and a cyclohexene ring without additional functional groups - **S:** An alcohol with two adjacent carbonyl groups and a cyclohexene ring **Explanation:** The reaction involves an aldol condensation between a simple ketone and a cyclic ketone under basic conditions with heat. This typically results in the formation of a β-hydroxy ketone product, which can further undergo dehydration to form an α,β-unsaturated ketone. Please analyze each structure to determine which could logically be the correct product of the aldol condensation based on typical reaction mechanisms.
Transcribed Image Text:**Aldol Reaction Analysis** **Question:** Predict the product of the aldol reaction shown below: - **Reactants:** - A ketone with a methyl group (acetone) - A cyclic ketone - **Reagents:** - Sodium hydroxide (NaOH) - Heat **Possible Products:** - **P:** A structure with a methyl ketone and an additional cyclohexane ring - **Q:** A structure with an alcohol group attached to the carbon adjacent to the carbonyl group and a cyclohexane ring - **R:** A structure featuring a methyl group and a cyclohexene ring without additional functional groups - **S:** An alcohol with two adjacent carbonyl groups and a cyclohexene ring **Explanation:** The reaction involves an aldol condensation between a simple ketone and a cyclic ketone under basic conditions with heat. This typically results in the formation of a β-hydroxy ketone product, which can further undergo dehydration to form an α,β-unsaturated ketone. Please analyze each structure to determine which could logically be the correct product of the aldol condensation based on typical reaction mechanisms.
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