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Practice Problems: For the below molecules, draw the chair conformation in its most stable stale. If both states have the same degree of stability, draw both.

Practice Problems: For the below molecules, draw the chair conformation in its most stable stale. If both states have the same degree of stability, draw both.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4. 5. 6. CI
Transcribed Image Text:4. 5. 6. CI
F. Stability of Cycloalkanes- Ring strain Among the cyclic compounds found in nature, 5 or 6 member ring compounds are most stable. 3 and 4 member ring are less stable- due to angle strain- Bayer Strain theory. Cyclic compoun ds can exist in puckered structure- more than 5 member rings are puckered and gain stability. Among different puckered conformations of cyclohexane, Chair conformation is more stable. When the re is /are substituents, use the following tips to determine which chair conformation is most stable. I. The largest substituent should be in the equatorial position. In the axial position, the substituent will experience 1,3 diaxial interactions (which is less stable). I. In the situation where two substituents are the same and one occupies the axial position while the other occupies the equatorial position, both chair conformations have the same degree of stability. Practice Problems: For the below molecules, draw the chair conformation in its most stable stale. If both states have the same degree of stability, draw both. 1.
Transcribed Image Text:F. Stability of Cycloalkanes- Ring strain Among the cyclic compounds found in nature, 5 or 6 member ring compounds are most stable. 3 and 4 member ring are less stable- due to angle strain- Bayer Strain theory. Cyclic compoun ds can exist in puckered structure- more than 5 member rings are puckered and gain stability. Among different puckered conformations of cyclohexane, Chair conformation is more stable. When the re is /are substituents, use the following tips to determine which chair conformation is most stable. I. The largest substituent should be in the equatorial position. In the axial position, the substituent will experience 1,3 diaxial interactions (which is less stable). I. In the situation where two substituents are the same and one occupies the axial position while the other occupies the equatorial position, both chair conformations have the same degree of stability. Practice Problems: For the below molecules, draw the chair conformation in its most stable stale. If both states have the same degree of stability, draw both. 1.
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