Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
 alt="3. Your experiment shows 1500 mL of a gas at 100°C. Convert each of those quantities
the proper units for the Ideal Gas Law.
The ideal gas law works best at high temperatures and high pressures because this is when gasses best follow the
Kinetic Molecular Theory.
Examples:
1. A 5.60 L sample of an ideal gas contains 0.954 moles at 0.976 atm. Calculate the temperature.
P
PV = nRT
,976 atm (a76atm)(S.60L)=(.a suma)
5.60L
.954 mol
0821
%3D
Gas Law Calculations
CFS
1. Write the equation
PV = nRT
V
(.0820)T
T=64.8L以
2. List the variables
3. Annotate the
question to find th
R
T
otov
variables
4. Convert to Land
. What volume is occupied by 19.6 moles of methane, CHa, at 27°C and 1.59atm?
P
if needed
PEV=nRT
(1.sam)V{19,6 moillo821qua
1.59 atm
5. Substitute the
variables you h
V
(and R) into th
196mol
.0821atm
T 27c+273
equation
6. Solve for the
missing varia
7. Round corre
and include
R
V=303 L
Practice
1.
Determine the volume occupied by 0.582 mol of oxygen gas at 285K and 7 atm.
PV = nRT
%3D
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