Polyethylene is made up of the following fractional distribution. Fraction Molecular Weight (Da) 5,000 10,000 1,000,000 Number of chairs 1 1000 2 1000 3 a. Calculate the weight average molecular weight (MW) of the polymer. b. Calculate the number average MW of the polymer. c. Calculate the poly dispersity

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Polyethylene is made up of the following fractional distribution.
Number of chairs
Molecular Weight (Da)
5,000
10,000
1,000,000
Fraction
1
1000
1000
3
a. Calculate the weight average molecular weight (Mw) of the polymer.
b. Calculate the number average MW of the polymer.
c. Calculate the poly dispersity
d. Which average molecular weight determination did the fraction 3 most significantly affect
and Why?
e. What would be the volume of a sample (100g) if the density of the polymer is 0.95 g/cc?
f. What is the best way of making this polymer: free radical, condensation, etc?
Transcribed Image Text:Polyethylene is made up of the following fractional distribution. Number of chairs Molecular Weight (Da) 5,000 10,000 1,000,000 Fraction 1 1000 1000 3 a. Calculate the weight average molecular weight (Mw) of the polymer. b. Calculate the number average MW of the polymer. c. Calculate the poly dispersity d. Which average molecular weight determination did the fraction 3 most significantly affect and Why? e. What would be the volume of a sample (100g) if the density of the polymer is 0.95 g/cc? f. What is the best way of making this polymer: free radical, condensation, etc?
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