Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please explain both thoroughly.

Transcribed Image Text:**Question 4: Suggest the Synthetic Method of Producing the Compound Below**
The image displays a chemical structure of a compound. This compound consists of a benzene ring attached to a propyl group. The compound can be identified as isopropylbenzene, commonly known as cumene.
**Detailed Explanation of the Chemical Structure:**
- **Aromatic Ring:** The structure contains a hexagonal benzene ring, indicated by alternating single and double bonds. The benzene ring is a six-carbon ring characterized by resonance stability due to these alternating bonds.
- **Propyl Group:** Attached to the benzene ring is a three-carbon side chain. This is a branched alkyl group, specifically an isopropyl group, where the central carbon atom is connected to two other carbon atoms and the benzene ring.
**Suggested Synthetic Method:**
A common method of synthesizing cumene is through the Friedel-Crafts alkylation of benzene. This involves reacting benzene with propylene (propene) in the presence of a strong acid catalyst, such as aluminum chloride (AlCl₃), to facilitate the formation of the isopropyl group on the benzene ring.
![**[5] Write a mechanism for the reaction below.**
**Reactants:**
- Acetic anhydride (structure shown with two acetyl groups connected by an oxygen atom)
- Benzene (hexagonal ring structure with alternating double bonds)
**Reagents:**
1. AlBr₃ (Aluminum bromide)
2. H₂O (Water)
**Description:**
This reaction illustrates an electrophilic aromatic substitution, commonly known as Friedel-Crafts acylation. The mechanism involves the formation of an acylium ion intermediate, which reacts with benzene in the presence of a Lewis acid catalyst, aluminum bromide. The final step involves hydrolysis to yield an aromatic ketone product.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd5563a1d-bff2-4a1d-a7e0-2fd1b448a5c7%2Fb4cd0348-f47d-48ec-a781-08c5f964e360%2F6hhgzwm_processed.png&w=3840&q=75)
Transcribed Image Text:**[5] Write a mechanism for the reaction below.**
**Reactants:**
- Acetic anhydride (structure shown with two acetyl groups connected by an oxygen atom)
- Benzene (hexagonal ring structure with alternating double bonds)
**Reagents:**
1. AlBr₃ (Aluminum bromide)
2. H₂O (Water)
**Description:**
This reaction illustrates an electrophilic aromatic substitution, commonly known as Friedel-Crafts acylation. The mechanism involves the formation of an acylium ion intermediate, which reacts with benzene in the presence of a Lewis acid catalyst, aluminum bromide. The final step involves hydrolysis to yield an aromatic ketone product.
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