Please answer all of them

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer all of them
7. For the terpene biosynthesis shown below, use arrow-pushing to depict the carbon-carbon bond
formation or "head-to-tail" coupling of the five carbon building blocks. Remember that the
pyrophosphate leaving group must be activated by a metal, so use Mg²+.
OPP
OPP
OPP =
V. SYNTHESIS Complete the syntheses below by showing all intermediate compounds, all necessary
reagents/conditions/work-up steps. Each synthesis requires multiple steps. To receive full credit, the
conditions and order of steps must maximize selectivity for the desired product.
1. Provide ALL the appropriate reagents or the CORRECT products in the sequence below.
Br2, FeBr3
1. H₂CMgBr
2. H₂0+
H3C
CH₂ OH
O
OH
PdCl₂(PPH3)2
Na₂CO3
1. SOCI₂
2. FeCl3
2. Perform a retrosynthesis that illustrates how the compound below could be prepared from chlorobenzene.
Include all reagents and intermediate compounds.
NO₂
ÖH
CO₂H
CI
Transcribed Image Text:7. For the terpene biosynthesis shown below, use arrow-pushing to depict the carbon-carbon bond formation or "head-to-tail" coupling of the five carbon building blocks. Remember that the pyrophosphate leaving group must be activated by a metal, so use Mg²+. OPP OPP OPP = V. SYNTHESIS Complete the syntheses below by showing all intermediate compounds, all necessary reagents/conditions/work-up steps. Each synthesis requires multiple steps. To receive full credit, the conditions and order of steps must maximize selectivity for the desired product. 1. Provide ALL the appropriate reagents or the CORRECT products in the sequence below. Br2, FeBr3 1. H₂CMgBr 2. H₂0+ H3C CH₂ OH O OH PdCl₂(PPH3)2 Na₂CO3 1. SOCI₂ 2. FeCl3 2. Perform a retrosynthesis that illustrates how the compound below could be prepared from chlorobenzene. Include all reagents and intermediate compounds. NO₂ ÖH CO₂H CI
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