Planning A Grignard Synthesis: (1) Identify the Degree of the Alcohol (2) Identify the Carbonyl Functional Class any (3) Identify the Grignard Reagent-Since a Grignard reagent is a stable carbanions such as MeX, 1°RX and Phx. 98° Sther aldeh 10
Planning A Grignard Synthesis: (1) Identify the Degree of the Alcohol (2) Identify the Carbonyl Functional Class any (3) Identify the Grignard Reagent-Since a Grignard reagent is a stable carbanions such as MeX, 1°RX and Phx. 98° Sther aldeh 10
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 64AP: The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold...
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The alcohol name is : 2 butanol
![Planning A Grignard Synthesis:
(1) Identify the Degree of the Alcohol 18
(2) Identify the Carbonyl Functional Class any Sther aldehudo
(3) Identify the Grignard Reagent- Since a Grignard reagent is a
stable carbanions such as MeX, 1°RX and Phx.
use halides that give rise to
Problem: Give the order of stability of carbanions:
(4) Keep water away from a Grignard reagent- Water
irreversible, corresponding
the alcolate. (5) C6H6MgBr + CO, → A
a Grignard reagent producing the
of the halide and Mg(OH)X equilibrium lies in favor of the alkane and not
A
H30 ->
Propose a synthesls for:
1. (a) 1-ethyl-2-methyl-1-cyclohexanol from2-methylcyclohexanone and the correct Grignard reagent.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F708ddd4f-13e8-43ea-aa99-3a81a016ec23%2Fc335141d-90a8-4a61-8652-f4e9a39e23f8%2Fmd1n8f_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Planning A Grignard Synthesis:
(1) Identify the Degree of the Alcohol 18
(2) Identify the Carbonyl Functional Class any Sther aldehudo
(3) Identify the Grignard Reagent- Since a Grignard reagent is a
stable carbanions such as MeX, 1°RX and Phx.
use halides that give rise to
Problem: Give the order of stability of carbanions:
(4) Keep water away from a Grignard reagent- Water
irreversible, corresponding
the alcolate. (5) C6H6MgBr + CO, → A
a Grignard reagent producing the
of the halide and Mg(OH)X equilibrium lies in favor of the alkane and not
A
H30 ->
Propose a synthesls for:
1. (a) 1-ethyl-2-methyl-1-cyclohexanol from2-methylcyclohexanone and the correct Grignard reagent.
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