Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. Draw the mechanism for this reaction

Transcribed Image Text:**Figure 28: 7-hydroxy-4-methylcoumarin Synthesis from Resorcinol & Ethyl Acetoacetate**
The image shows a chemical reaction for synthesizing 7-hydroxy-4-methylcoumarin. The reaction involves the following components:
- **Reactants:**
- Resorcinol (Chemical structure: a benzene ring with two hydroxyl groups at positions 1 and 3)
- Ethyl acetoacetate (Chemical structure: a ketone group adjacent to an ester group)
- **Conditions:**
- **Amberlyst-15**: A catalyst used in the reaction
- **Toluene**: Used as the solvent
- **Product:**
- 7-hydroxy-4-methylcoumarin (Chemical structure: a benzene ring fused with a pyrone ring, hydroxyl group at position 7)
**Pre-Lab Questions:**
- Draw the mechanism for this reaction.
**Explanation:**
This reaction is typically a Pechmann condensation, an organic reaction to synthesize coumarins. The page instructs students to draw the detailed mechanism, illustrating the electron movement and intermediate structures involved during the synthesis process.
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