Photoelectron spectroscopy applies the principle of the photoelectric effect to study orbital energies of atoms and molecules. High-energy radiation (usually UV or x-ray) is absorbed by a sample and an electron is ejected. The orbital energy can be calculated from the known energy of the radiation and the measured energy of the electron lost. The following energy differences were determined for several electron transitions: AE2+1 = 4.098 × 10-17 J AE5-1 = 5.242 × 10-¹7 J AE3-1 = 4.854 × 10-¹7 J AE4-2 = 1.024 × 10-¹7 J Calculate AE and λ of a photon emitted in the following transitions: (a) level 3 → 2; (b) level 4 → 1; (c) level 5 4.
Photoelectron spectroscopy applies the principle of the photoelectric effect to study orbital energies of atoms and molecules. High-energy radiation (usually UV or x-ray) is absorbed by a sample and an electron is ejected. The orbital energy can be calculated from the known energy of the radiation and the measured energy of the electron lost. The following energy differences were determined for several electron transitions: AE2+1 = 4.098 × 10-17 J AE5-1 = 5.242 × 10-¹7 J AE3-1 = 4.854 × 10-¹7 J AE4-2 = 1.024 × 10-¹7 J Calculate AE and λ of a photon emitted in the following transitions: (a) level 3 → 2; (b) level 4 → 1; (c) level 5 4.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Photoelectron spectroscopy applies the principle of the
photoelectric effect to study orbital energies of atoms and
molecules. High-energy radiation (usually UV or x-ray) is absorbed
by a sample and an electron is ejected. The orbital energy can be
calculated from the known energy of the radiation and the
measured energy of the electron lost. The following energy
differences were determined for several electron transitions:
ΔΕ2–1 : 4.098 × 10-¹7 J
AE5-1 = 5.242 × 10-¹7 J
ΔΕ3-1
-
= 4.854 × 10-17 J
AE4-2= 1.024 × 10-¹7 J
Calculate AE and λ of a photon emitted in the following transitions: (a)
level 3 → 2; (b) level 4 → 1; (c) level 5 → 4.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbbfd9059-98dd-45b5-ad53-13fd42a280fd%2F2cdc5a64-fe91-47b6-9196-92d283cfd963%2F4ulvjxm_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Photoelectron spectroscopy applies the principle of the
photoelectric effect to study orbital energies of atoms and
molecules. High-energy radiation (usually UV or x-ray) is absorbed
by a sample and an electron is ejected. The orbital energy can be
calculated from the known energy of the radiation and the
measured energy of the electron lost. The following energy
differences were determined for several electron transitions:
ΔΕ2–1 : 4.098 × 10-¹7 J
AE5-1 = 5.242 × 10-¹7 J
ΔΕ3-1
-
= 4.854 × 10-17 J
AE4-2= 1.024 × 10-¹7 J
Calculate AE and λ of a photon emitted in the following transitions: (a)
level 3 → 2; (b) level 4 → 1; (c) level 5 → 4.
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