Phosphoric acid is triprotic with the step-wise dissociation shown below.  A 0.92 M phosphoric acid solution is prepared.  Calculate the equilibrium concentrations of the species indicated.  Report all answers in scientific notation using 2 sig figs.  Rather than use the quadratic equation, you can make assumptions like we do in class (ie if K<<1, then 0.1-x ~ 0.1) H3PO4H3PO4  +  H2OH2O  ↔↔   H2PO−4H2PO4-   +  H3O+H3O+   Ka1=7.5x10−3Ka1=7.5x10-3                      H2PO−4H2PO4-    + H2OH2O  ↔↔   HPO2−4HPO42-  + H3O+H3O+   Ka2=6.2x10−8Ka2=6.2x10-8                    HPO2−4HPO42-  + H2OH2O  ↔↔  PO3−4PO43-  +  H3O+H3O+ Ka3=4.8x10−13Ka3=4.8x10-13                           What is the pH of this solution?   Report pH as a number and not in scientific notation.

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Phosphoric acid is triprotic with the step-wise dissociation shown below.  A 0.92 M phosphoric acid solution is prepared.  Calculate the equilibrium concentrations of the species indicated.  Report all answers in scientific notation using 2 sig figs.  Rather than use the quadratic equation, you can make assumptions like we do in class (ie if K<<1, then 0.1-x ~ 0.1)

H3PO4H3PO4  H2OH2O  ↔↔   H2PO−4H2PO4-   +  H3O+H3O+   Ka1=7.5x10−3Ka1=7.5x10-3 
                  
 H2PO−4H2PO4-    + H2OH2O  ↔↔   HPO2−4HPO42-  + H3O+H3O+   Ka2=6.2x10−8Ka2=6.2x10-8 
                 
HPO2−4HPO42-  + H2OH2O  ↔↔  PO3−4PO43-  +  H3O+H3O+ Ka3=4.8x10−13Ka3=4.8x10-13 
                      

 

What is the pH of this solution?  

Report pH as a number and not in scientific notation.  

 

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