pH 7.20 5.83 4.32 Col? า [H] (mol/L) 2.9 x 10-12 1.5×1 5.4 x 10-⁹ b. 267 [OH-] (mol/L) 6.7 x 10-⁹ 8.8 x 104 2 Acid/Base Sol'n? ACiDic

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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D Q1 please fill table Q 2 please write F- reaction
### I. Arrhenius Acids and Bases

- **Acid** - any substance which delivers \[ \text{H}^+ \] to the solution.
- **Base** - any substance which delivers \[ \text{OH}^- \] to the solution.

### II. pH

pH is defined as the negative logarithm of the hydrogen or hydronium ion concentration:

\[ \text{pH} = -\log [\text{H}^+] = -\log [\text{H}_3\text{O}^+] \]

**Exercise 1: Complete the Table**

| pH  | \[ \text{H}^+ \] (mol/L) | \[ \text{OH}^- \] (mol/L) | Acid/Base Sol'n? |
|-----|--------------------------|--------------------------|------------------|
| 7.20| 2.9 x 10⁻¹²              |                          |                  |
| 5.83| 1.5 x 10⁻⁶               | 6.7 x 10⁻⁹               | ACIDIC           |
| 4.32|                          |                          |                  |

### Notes and Calculations

- \[ [\text{OH}^- ] \approx 6.7 \times 10^{-9} \]
- \( K_w = [\text{H}^+][\text{OH}^- ] \)
- \[ \text{pH} = -\log (1.5 \times 10^{-6}) \]

These notes indicate calculation points and steps for understanding the relationship and conversions between pH, \[ \text{H}^+ \] ions, and \[ \text{OH}^- \] ions, as well as identifying the nature of the solution (acidic or basic).
Transcribed Image Text:### I. Arrhenius Acids and Bases - **Acid** - any substance which delivers \[ \text{H}^+ \] to the solution. - **Base** - any substance which delivers \[ \text{OH}^- \] to the solution. ### II. pH pH is defined as the negative logarithm of the hydrogen or hydronium ion concentration: \[ \text{pH} = -\log [\text{H}^+] = -\log [\text{H}_3\text{O}^+] \] **Exercise 1: Complete the Table** | pH | \[ \text{H}^+ \] (mol/L) | \[ \text{OH}^- \] (mol/L) | Acid/Base Sol'n? | |-----|--------------------------|--------------------------|------------------| | 7.20| 2.9 x 10⁻¹² | | | | 5.83| 1.5 x 10⁻⁶ | 6.7 x 10⁻⁹ | ACIDIC | | 4.32| | | | ### Notes and Calculations - \[ [\text{OH}^- ] \approx 6.7 \times 10^{-9} \] - \( K_w = [\text{H}^+][\text{OH}^- ] \) - \[ \text{pH} = -\log (1.5 \times 10^{-6}) \] These notes indicate calculation points and steps for understanding the relationship and conversions between pH, \[ \text{H}^+ \] ions, and \[ \text{OH}^- \] ions, as well as identifying the nature of the solution (acidic or basic).
**VIII. Base Equilibria**

Just as with acids, strong bases react with water to produce 100% products while weak bases do not. For weak bases, the reaction always produces hydroxide ions and the conjugate acid of the base.

**Exercise I**

Write \( K_b \) (hydrolysis) reactions for the following bases. Use the proper type of arrow in your reaction.

1. \( \text{C}_2\text{H}_3\text{O}_2^- (\text{aq}) + \text{H}_2\text{O} (\text{l}) \rightleftharpoons \text{HC}_2\text{H}_3\text{O}_2 (\text{aq}) + \text{OH}^- (\text{aq}) \)

2. \( \text{LiOH (s)} \rightarrow \text{Li}^+ (\text{aq}) + \text{OH}^- (\text{aq}) \)

**Exercise II**

Calculate the pH of the following solutions of strong bases:
a) 3.7 x 10^-3 M KOH
Transcribed Image Text:**VIII. Base Equilibria** Just as with acids, strong bases react with water to produce 100% products while weak bases do not. For weak bases, the reaction always produces hydroxide ions and the conjugate acid of the base. **Exercise I** Write \( K_b \) (hydrolysis) reactions for the following bases. Use the proper type of arrow in your reaction. 1. \( \text{C}_2\text{H}_3\text{O}_2^- (\text{aq}) + \text{H}_2\text{O} (\text{l}) \rightleftharpoons \text{HC}_2\text{H}_3\text{O}_2 (\text{aq}) + \text{OH}^- (\text{aq}) \) 2. \( \text{LiOH (s)} \rightarrow \text{Li}^+ (\text{aq}) + \text{OH}^- (\text{aq}) \) **Exercise II** Calculate the pH of the following solutions of strong bases: a) 3.7 x 10^-3 M KOH
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