Answered: Peptide-1 -C-SR NH-ÇH-C- ´NH-CH-C-…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Native chemical ligation works by sequential nucleophilic acyl substitution reactions, but the mechanism depicting this in Figure 1 is not correct. Using your knowledge of nucleophilic acyl substitution, redraw the mechanism in Figure 1 so that it is chemically correct. Make sure to depict all of the tetrahedral intermediates and proton transfer steps.

Peptide-1
C-SR NH CH-C
Peptide-2
Chemoselective
reaction
-NH,
Peptide-1
CH-C
Peptide-2
Spontaneous
rearrangement
Peptide-1
C-NH-CH-C-
Peptide-2
SH

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