Part A The formation of CsCl from Cs(s) and Cl2 (g) involves the following steps: 1. Cs(s)→Cs(g) 2. Cl2 (g)→Cl(g) 3. Cs(g)→Cs+ (g) +e¯ 4. Cl(g) +e¯→Cl¯(g) 5. Cs* (g) + Cl¯ (g)→CSC1(s) Which of these steps absorb energy and which release energy? Drag the items to the appropriate bin. • View Available Hint(s)

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Please answer question 16 part A and C

**Electrostatic Attraction and Ionic Bond Formation**

The electrostatic attraction between oppositely charged ions is called an *ionic bond*. The net energy change in the formation of an ionic bond is a composite of five steps, which can involve energy absorption or release. These steps for a generic metal, M, and a diatomic halogen, X₂, include:

1. **Sublimation of the metal**
2. **Dissociation of the X–X bond**
3. **Ionization of the metal**
4. **Transfer of the electron to X**
5. **Crystalline solid formation**

The overall energy transfer is the sum of the energy changes for each step. The **magnitude of the potential energy** of two interacting charges, E (related to Lattice energy), reflects the strength of ionic attraction. It is calculated as:

\[ E = \frac{1}{4\pi\epsilon_0} \frac{q_1 \times q_2}{d} = k \frac{q_1 \times q_2}{d} \]

Where:
- \( k \) is a constant \( \left(\frac{1}{4\pi\epsilon_0} = \frac{1}{1.11 \times 10^{-10} \, \text{C}^2/(\text{J} \cdot \text{m})}\right) \)
- \( q_1 \) and \( q_2 \) are charges of the ions
- \( d \) is the distance between ion nuclei

**Part A**

For the formation of CsCl from Cs(s) and Cl₂(g), the steps are:

1. Cs(s) → Cs(g)
2. \( \frac{1}{2} \) Cl₂(g) → Cl(g)
3. Cs(g) → Cs⁺(g) + e⁻
4. Cl(g) + e⁻ → Cl⁻(g)
5. Cs⁺(g) + Cl⁻(g) → CsCl(s)

**Activity:**
Identify which steps absorb or release energy by placing the steps in the appropriate categories.

**Diagram Explanation:**

The interactive diagram allows users to drag steps to categorize them under "Absorbs energy" or "Releases energy." There are buttons labeled 1 to 5 representing each step. Users can click 'Reset' to start over and
Transcribed Image Text:**Electrostatic Attraction and Ionic Bond Formation** The electrostatic attraction between oppositely charged ions is called an *ionic bond*. The net energy change in the formation of an ionic bond is a composite of five steps, which can involve energy absorption or release. These steps for a generic metal, M, and a diatomic halogen, X₂, include: 1. **Sublimation of the metal** 2. **Dissociation of the X–X bond** 3. **Ionization of the metal** 4. **Transfer of the electron to X** 5. **Crystalline solid formation** The overall energy transfer is the sum of the energy changes for each step. The **magnitude of the potential energy** of two interacting charges, E (related to Lattice energy), reflects the strength of ionic attraction. It is calculated as: \[ E = \frac{1}{4\pi\epsilon_0} \frac{q_1 \times q_2}{d} = k \frac{q_1 \times q_2}{d} \] Where: - \( k \) is a constant \( \left(\frac{1}{4\pi\epsilon_0} = \frac{1}{1.11 \times 10^{-10} \, \text{C}^2/(\text{J} \cdot \text{m})}\right) \) - \( q_1 \) and \( q_2 \) are charges of the ions - \( d \) is the distance between ion nuclei **Part A** For the formation of CsCl from Cs(s) and Cl₂(g), the steps are: 1. Cs(s) → Cs(g) 2. \( \frac{1}{2} \) Cl₂(g) → Cl(g) 3. Cs(g) → Cs⁺(g) + e⁻ 4. Cl(g) + e⁻ → Cl⁻(g) 5. Cs⁺(g) + Cl⁻(g) → CsCl(s) **Activity:** Identify which steps absorb or release energy by placing the steps in the appropriate categories. **Diagram Explanation:** The interactive diagram allows users to drag steps to categorize them under "Absorbs energy" or "Releases energy." There are buttons labeled 1 to 5 representing each step. Users can click 'Reset' to start over and
**Part C**

Consider the lattice energy of any ionic compound. What combination of ions and charges will produce the largest (in magnitude) lattice energies?

- View Available Hint(s)

**Options:**
- small ions and small charges
- large ions and large charges
- small ions and large charges
- large ions and small charges
Transcribed Image Text:**Part C** Consider the lattice energy of any ionic compound. What combination of ions and charges will produce the largest (in magnitude) lattice energies? - View Available Hint(s) **Options:** - small ions and small charges - large ions and large charges - small ions and large charges - large ions and small charges
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