Part A The formation of CsCl from Cs(s) and Cl2 (g) involves the following steps: 1. Cs(s)→Cs(g) 2. Cl2 (g)→Cl(g) 3. Cs(g)→Cs+ (g) +e¯ 4. Cl(g) +e¯→Cl¯(g) 5. Cs* (g) + Cl¯ (g)→CSC1(s) Which of these steps absorb energy and which release energy? Drag the items to the appropriate bin. • View Available Hint(s)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Please answer question 16 part A and C
![**Electrostatic Attraction and Ionic Bond Formation**
The electrostatic attraction between oppositely charged ions is called an *ionic bond*. The net energy change in the formation of an ionic bond is a composite of five steps, which can involve energy absorption or release. These steps for a generic metal, M, and a diatomic halogen, X₂, include:
1. **Sublimation of the metal**
2. **Dissociation of the X–X bond**
3. **Ionization of the metal**
4. **Transfer of the electron to X**
5. **Crystalline solid formation**
The overall energy transfer is the sum of the energy changes for each step. The **magnitude of the potential energy** of two interacting charges, E (related to Lattice energy), reflects the strength of ionic attraction. It is calculated as:
\[ E = \frac{1}{4\pi\epsilon_0} \frac{q_1 \times q_2}{d} = k \frac{q_1 \times q_2}{d} \]
Where:
- \( k \) is a constant \( \left(\frac{1}{4\pi\epsilon_0} = \frac{1}{1.11 \times 10^{-10} \, \text{C}^2/(\text{J} \cdot \text{m})}\right) \)
- \( q_1 \) and \( q_2 \) are charges of the ions
- \( d \) is the distance between ion nuclei
**Part A**
For the formation of CsCl from Cs(s) and Cl₂(g), the steps are:
1. Cs(s) → Cs(g)
2. \( \frac{1}{2} \) Cl₂(g) → Cl(g)
3. Cs(g) → Cs⁺(g) + e⁻
4. Cl(g) + e⁻ → Cl⁻(g)
5. Cs⁺(g) + Cl⁻(g) → CsCl(s)
**Activity:**
Identify which steps absorb or release energy by placing the steps in the appropriate categories.
**Diagram Explanation:**
The interactive diagram allows users to drag steps to categorize them under "Absorbs energy" or "Releases energy." There are buttons labeled 1 to 5 representing each step. Users can click 'Reset' to start over and](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fded90a0e-1aa2-42d3-8902-387fb21746ad%2F9a52ea60-32bb-4783-963d-3558b47f2c64%2Fznryft6_processed.png&w=3840&q=75)
![**Part C**
Consider the lattice energy of any ionic compound. What combination of ions and charges will produce the largest (in magnitude) lattice energies?
- View Available Hint(s)
**Options:**
- small ions and small charges
- large ions and large charges
- small ions and large charges
- large ions and small charges](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fded90a0e-1aa2-42d3-8902-387fb21746ad%2F9a52ea60-32bb-4783-963d-3558b47f2c64%2Fknn0myh_processed.png&w=3840&q=75)
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