P7F.9 In this problem you will establish the commutation relations, given in eqn 7E. 14, between the operators for the x-, y-, and z-components of angular momentum, which are defined in eqn 7F.13. In order to manipulate the operators correctly it is helpful to imagine that they are acting on some arbitrary function f: it does not matter what fis, and at the end of the proof it is simply removed. Consider [,,1,] = ,-11. Consider the effect of the first term on some arbitrary function fand evaluate A D -x dx se The next step is to multiply out the parentheses, and in doing so care needs to be taken over the order of operations. (b) Repeat the procedure for the other term in the commutator, 1,1, f. (c) Combine the results from (a) and (b) so as to evaluate l f-11f;you should find that many of the terms cancel. Confirm that the final expression you have is indeed iħl_f, where l̟ is given in eqn 7F.13. (d) The definitions in eqn 7E.13 are related to one another by cyclic permutation of the x, y, and z. That is, by making the permutation x→y, yz, and z→x, you can move from one definition to the next: confirm that this is so. (e) The same cyclic permutation can be applied to the commutators of these operators. Start with [!, 1,]=ihl, and show that cyclic permutation generates the other two commutators in eqn 7F.14.
P7F.9 In this problem you will establish the commutation relations, given in eqn 7E. 14, between the operators for the x-, y-, and z-components of angular momentum, which are defined in eqn 7F.13. In order to manipulate the operators correctly it is helpful to imagine that they are acting on some arbitrary function f: it does not matter what fis, and at the end of the proof it is simply removed. Consider [,,1,] = ,-11. Consider the effect of the first term on some arbitrary function fand evaluate A D -x dx se The next step is to multiply out the parentheses, and in doing so care needs to be taken over the order of operations. (b) Repeat the procedure for the other term in the commutator, 1,1, f. (c) Combine the results from (a) and (b) so as to evaluate l f-11f;you should find that many of the terms cancel. Confirm that the final expression you have is indeed iħl_f, where l̟ is given in eqn 7F.13. (d) The definitions in eqn 7E.13 are related to one another by cyclic permutation of the x, y, and z. That is, by making the permutation x→y, yz, and z→x, you can move from one definition to the next: confirm that this is so. (e) The same cyclic permutation can be applied to the commutators of these operators. Start with [!, 1,]=ihl, and show that cyclic permutation generates the other two commutators in eqn 7F.14.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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