P.mr rd...d.. ..rar l all. a.. lul l..ll.l. aCullano: IR peak at 26 DO 200 em-1: NMR (Ppm): 0.0 (triplet. GI) 1.5 (quartet. 4I1) Rpeuk al 30D0 285o em-4: NMR (Pin): 1.10 (dc bkt. reltive ureu - 5) .lal -1 > H NMR of M 3 H H NMR of N 3H 3H 3H 1H 3H 2H 2 H 2 H 2H 9. 4 9 8 7 6 pnm npm

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Treatment of (CH3)2CHCH(OH)CH2CH3 with TsOH affords two products
(M and N) with molecular formula C6H12. The 1H NMR spectra of M and N
are given below. Propose structures for M and N, and draw a mechanism
to explain their formation.

P.mr rd...d.. ..rar l all. a.. lul l..ll.l.
aCullano: IR peak at 26 DO 200 em-1: NMR (Ppm):
0.0 (triplet. GI) 1.5 (quartet. 4I1)
Rpeuk al 30D0 285o em-4: NMR (Pin):
1.10 (dc bkt. reltive ureu - 5)
.lal -1 >
H NMR of M
3 H
H NMR of N
3H
3H
3H
1H
3H
2H
2 H
2 H
2H
9.
4
9
8
7
6
pnm
npm
Transcribed Image Text:P.mr rd...d.. ..rar l all. a.. lul l..ll.l. aCullano: IR peak at 26 DO 200 em-1: NMR (Ppm): 0.0 (triplet. GI) 1.5 (quartet. 4I1) Rpeuk al 30D0 285o em-4: NMR (Pin): 1.10 (dc bkt. reltive ureu - 5) .lal -1 > H NMR of M 3 H H NMR of N 3H 3H 3H 1H 3H 2H 2 H 2 H 2H 9. 4 9 8 7 6 pnm npm
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