or the reaction: CO₂ (+ H₂O) H₂CO, where the parentheses indicate that H₂O is not included in the equilibrium constant expression or in the rate equation, the following data were obtained: . . A,H 4500 J/mol, AS-30J/(mol K) k₁ at 0 °C is 0.004/s kg at 22 °C is 0.048/s Assuming that A,H and A,Sº are independent of temperature in this range. 1. Calculate the equilibrium constant and ką values at 22°C. 2. Calculate the activation energy for the forward reaction.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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or the reaction: CO₂ (+ H₂O) <> H₂CO₂
ky
where the parentheses indicate that H₂O is not included in the equilibrium constant expression or in the rate
equation, the following data were obtained:
.
A,H=4500 J/mol,
4,5° = -30J/(mal K)
.
▸
k₁ at 0 °C is 0.004/s
k; at 22 °C is 0.048/s
Assuming that A,H and A,Sº are independent of temperature in this range.
1. Calculate the equilibrium constant and k₂ values at 22°C.
2. Calculate the activation energy for the forward reaction.
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Transcribed Image Text:or the reaction: CO₂ (+ H₂O) <> H₂CO₂ ky where the parentheses indicate that H₂O is not included in the equilibrium constant expression or in the rate equation, the following data were obtained: . A,H=4500 J/mol, 4,5° = -30J/(mal K) . ▸ k₁ at 0 °C is 0.004/s k; at 22 °C is 0.048/s Assuming that A,H and A,Sº are independent of temperature in this range. 1. Calculate the equilibrium constant and k₂ values at 22°C. 2. Calculate the activation energy for the forward reaction. Upload Choose a File
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