| NaOH IN 25x10³ Q3: In a carbonate mixture containing HCO, CO², and NaOH, either alone or combination. Each 40 mL of the mixture required 12 mL of 0.10 M HCI to reach the phenolphthalein indicator end point, and 30 mL to reach the bromocresol green indictor end point. Identify the mixture and calculate the molarity of each component.

| NaOH IN 25x10³ Q3: In a carbonate mixture containing HCO, CO², and NaOH, either alone or combination. Each 40 mL of the mixture required 12 mL of 0.10 M HCI to reach the phenolphthalein indicator end point, and 30 mL to reach the bromocresol green indictor end point. Identify the mixture and calculate the molarity of each component.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 93QRT: When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence...

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Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
Determine the dominant acid-base equilibrium that results when each of the following pairs of solutions is mixed. Indicate the equilibrium by writing 1 for a strong acid, 3 for a weak acid, 4 for an acidic buffer, 7 for a neutral solution, 10 for a basic buffer, 11 for a weak base, and 13 for a strong base. (a) 10.0 mL of 0.15 M NaOH + 15.0 mL of 0.10 M HNO3 (b) 25.0 mL of 0.10 M HCl + 10.0 mL of 0.25 M NH3 (c) 50.0 mL of 0.050 M NaOH + 50.0 mL of 0.10 M NH3 (d) 50.0 mL of 0.10 M NH3 + 50.0 mL of 0.05 M HCl
A 25.0-mL sample of hydroxylamine is titrated to the equivalence point with 35.8 mL of 0.150 M HCl. a What was the concentration of the original hydroxylamine solution? b What is the pH at the equivalence point? c Which indicators, bromphenol blue, methyl red, or phenolphthalein, should be used to detect the end point of the titration? Why?
What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.
A 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?
Which of the indicators in Fig. 14-8 could be used for the titrations in Exercises 61 and 63?
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetate
Given three acid-base indicatorsâ€”methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)â€”which would you select for the following acid-base titrations? (a) perchloric acid with an aqueous solution of ammonia (b) nitrous acid with lithium hydroxide (c) hydrobromic acid with strontium hydroxide (d) sodium fluoride with nitric acid
8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI solution require the same amount of 1.0 M NaOH to hit a titration end point? Explain.
Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a) before any NaOH is added? (b) at half-neutralization? (c) at the equivalence point? (d) when 0.10 mL less than the volume of NaOH to reach the equivalence point is added? (e) when 0.10 mL more than the volume of NaOH to reach the equivalence point is added? (f) Use your data to construct a plot similar to that shown in Figure 14.10 (pH versus volume NaOH added).

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