or each of the following molecules, construct the MOS from the 2p, atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC=CH НС—СН HC=CH НС —СH (b) Allyl radical H H H H C=C •C-C, H C-H H C-H H H Indicate which, if any, of these orbitals have identical ener- gies from symmetry considerations. Show the number of electrons occupying each w MO in the ground state, and indicate whether either or both of the molecules are para- magnetic. Assume that the C atoms in the allyl radical are all sp? hybridized. Activate io to S

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Chapter1: Chemical Foundations
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or each of the following molecules, construct the MOS
from the 2p, atomic orbitals perpendicular to the plane of
the carbon atoms.
(a) Cyclobutadiene HC=CH
НС—СН
HC=CH
НС —СH
(b) Allyl radical
H
H
H
H
C=C
•C-C,
H
C-H
H
C-H
H
H
Indicate which, if any, of these orbitals have identical ener-
gies from symmetry considerations. Show the number of
electrons occupying each w MO in the ground state, and
indicate whether either or both of the molecules are para-
magnetic. Assume that the C atoms in the allyl radical are
all sp? hybridized.
Activate
io to S
Transcribed Image Text:or each of the following molecules, construct the MOS from the 2p, atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC=CH НС—СН HC=CH НС —СH (b) Allyl radical H H H H C=C •C-C, H C-H H C-H H H Indicate which, if any, of these orbitals have identical ener- gies from symmetry considerations. Show the number of electrons occupying each w MO in the ground state, and indicate whether either or both of the molecules are para- magnetic. Assume that the C atoms in the allyl radical are all sp? hybridized. Activate io to S
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