or each of the following molecules, construct the MOS from the 2p, atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC=CH НС—СН HC=CH НС —СH (b) Allyl radical H H H H C=C •C-C, H C-H H C-H H H Indicate which, if any, of these orbitals have identical ener- gies from symmetry considerations. Show the number of electrons occupying each w MO in the ground state, and indicate whether either or both of the molecules are para- magnetic. Assume that the C atoms in the allyl radical are all sp? hybridized. Activate io to S
or each of the following molecules, construct the MOS from the 2p, atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC=CH НС—СН HC=CH НС —СH (b) Allyl radical H H H H C=C •C-C, H C-H H C-H H H Indicate which, if any, of these orbitals have identical ener- gies from symmetry considerations. Show the number of electrons occupying each w MO in the ground state, and indicate whether either or both of the molecules are para- magnetic. Assume that the C atoms in the allyl radical are all sp? hybridized. Activate io to S
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![or each of the following molecules, construct the MOS
from the 2p, atomic orbitals perpendicular to the plane of
the carbon atoms.
(a) Cyclobutadiene HC=CH
НС—СН
HC=CH
НС —СH
(b) Allyl radical
H
H
H
H
C=C
•C-C,
H
C-H
H
C-H
H
H
Indicate which, if any, of these orbitals have identical ener-
gies from symmetry considerations. Show the number of
electrons occupying each w MO in the ground state, and
indicate whether either or both of the molecules are para-
magnetic. Assume that the C atoms in the allyl radical are
all sp? hybridized.
Activate
io to S](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fab30c284-e9e0-4766-87eb-80579b67a34a%2F178c7e3a-4c1f-4071-a536-241ce41b85d8%2F1m7g5c.png&w=3840&q=75)
Transcribed Image Text:or each of the following molecules, construct the MOS
from the 2p, atomic orbitals perpendicular to the plane of
the carbon atoms.
(a) Cyclobutadiene HC=CH
НС—СН
HC=CH
НС —СH
(b) Allyl radical
H
H
H
H
C=C
•C-C,
H
C-H
H
C-H
H
H
Indicate which, if any, of these orbitals have identical ener-
gies from symmetry considerations. Show the number of
electrons occupying each w MO in the ground state, and
indicate whether either or both of the molecules are para-
magnetic. Assume that the C atoms in the allyl radical are
all sp? hybridized.
Activate
io to S
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