One of the chair conformations of cis-1-bromo-3-methylcyclohexane is more stable than the other by 14.0 kJ/mol. Use this, and the table below, to estimate the energy cost of a 1,3-diaxial interaction between a bromine atom and a methyl group. Substituent kJ/mol Substituent kJ/mol 1,3-Diaxial Strain Energies for Monosubstituted Cyclohexanes -CN, cyano -F -I -C=CH, ethynyl 0.85 -CI -Br -OH 0.4 -C6H5 0.5 0.95 1.1 1.2 1.95 6.3 -NH₂ -COOH 2.95 -CH3 2.95 -CH=CH₂ 3.55 3.64 -CH₂CH3 -CH(CH3)2 4.5 -C(CH3)3 3.65 10.5 (Round your answer to one decimal place.) kJ/mol
One of the chair conformations of cis-1-bromo-3-methylcyclohexane is more stable than the other by 14.0 kJ/mol. Use this, and the table below, to estimate the energy cost of a 1,3-diaxial interaction between a bromine atom and a methyl group. Substituent kJ/mol Substituent kJ/mol 1,3-Diaxial Strain Energies for Monosubstituted Cyclohexanes -CN, cyano -F -I -C=CH, ethynyl 0.85 -CI -Br -OH 0.4 -C6H5 0.5 0.95 1.1 1.2 1.95 6.3 -NH₂ -COOH 2.95 -CH3 2.95 -CH=CH₂ 3.55 3.64 -CH₂CH3 -CH(CH3)2 4.5 -C(CH3)3 3.65 10.5 (Round your answer to one decimal place.) kJ/mol
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:One of the chair conformations of cis-1-bromo-3-methylcyclohexane is more stable than the other by 14.0 kJ/mol. Use this, and the table below, to estimate the
energy cost of a 1,3-diaxial interaction between a bromine atom and a methyl group.
Substituent kJ/mol Substituent kJ/mol
1,3-Diaxial Strain Energies for Monosubstituted
Cyclohexanes
-CN, cyano
-F
-I
-C=CH, ethynyl 0.85
-CI
-Br
-OH
-C6Hs
0.4
0.5
Submit Answer
0.95
1.1
1.2
1.95
6.3
-NH₂
-COOH
2.95
2.95
-CH=CH₂
-CH3
-CH₂CH3
-CH(CH3)2 4.5
-C(CH3)3 10.5
Try Another Version
3.55
3.64
(Round your answer to one decimal place.)
kJ/mol
3.65
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