One of 7.74 There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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7.74 There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of
these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times
faster than the reaction of the other isomer. Identify the isomer that reacts faster,
and explain the difference in rate for these two isomers.
7.75 Substitution vs. Elimination: Identify the major and minor product(s) for
each of the following reactions:
i
?
a.
b.
C.
d.
8.
h.
k.
Answer
Br
Br
OH
Br
Br
Br
Br
1-BUOK
NaOH
NaOEt
NaOEt
OTS
NaOH
?
?
NaOEt
EtOH
1-BUOK
NaOEt
EtOH
NaOMe
?
conc. H₂SO4
Heat
NaCl
DMSO
?
?
?
?
?
?
?
Transcribed Image Text:7.74 There are two stereoisomers of 1-tert-butyl-4-chloro-cyclohexane. One of these isomers reacts with sodium ethoxide in an E2 reaction that is 500 times faster than the reaction of the other isomer. Identify the isomer that reacts faster, and explain the difference in rate for these two isomers. 7.75 Substitution vs. Elimination: Identify the major and minor product(s) for each of the following reactions: i ? a. b. C. d. 8. h. k. Answer Br Br OH Br Br Br Br 1-BUOK NaOH NaOEt NaOEt OTS NaOH ? ? NaOEt EtOH 1-BUOK NaOEt EtOH NaOMe ? conc. H₂SO4 Heat NaCl DMSO ? ? ? ? ? ? ?
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