One mechanism for the destruction of ozone in the upper atmosphere is Оз (9) + NO(9) NO,(9) + O2(9) Slow NO2(9) + O(g) → NO(g) + O2(9) Fast Overall reaction O3(g) + O(g) → 20,(9) a. Which species is a catalyst? 02 ONO O03 NO2 b. Which species is an intermediate? O2 NO2 O 03 NO c. Ea for the uncatalyzed reaction 03 (9) + 0(g) → 20,(g) is 14.0 kJ. Ea for the same reaction when catalyzed is11.9 kJ. What is the ratio of the rate constant for the catalyzed reaction to that for the uncatalyzed reaction at 29°C? Assume the frequency factor A is the same for each reaction. Ratio =

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Chapter1: Chemical Foundations
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One mechanism for the destruction of ozone in the upper atmosphere is
O3 (9) + NO(g) → NO,(g) + O2(9) Slow
NO2 (g) + O(g) → NO(g) + O2 (g) Fast
Overall reaction O3(g) + O(g) → 20,(g)
a. Which species is a catalyst?
O02
ΟΝΟ
O3
NO2
b. Which species is an intermediate?
O2
NO2
O 03
ΟΝΟ
c. Ea for the uncatalyzed reaction
O3 (g) + O(g) → 20,(g)
is 14.0 kJ.
E, for the same reaction when catalyzed is11.9 kJ. What is the ratio of the
rate constant for the catalyzed reaction to that for the uncatalyzed reaction
at 29°C? Assume the frequency factor
A is the same for each reaction.
Ratio =
Transcribed Image Text:One mechanism for the destruction of ozone in the upper atmosphere is O3 (9) + NO(g) → NO,(g) + O2(9) Slow NO2 (g) + O(g) → NO(g) + O2 (g) Fast Overall reaction O3(g) + O(g) → 20,(g) a. Which species is a catalyst? O02 ΟΝΟ O3 NO2 b. Which species is an intermediate? O2 NO2 O 03 ΟΝΟ c. Ea for the uncatalyzed reaction O3 (g) + O(g) → 20,(g) is 14.0 kJ. E, for the same reaction when catalyzed is11.9 kJ. What is the ratio of the rate constant for the catalyzed reaction to that for the uncatalyzed reaction at 29°C? Assume the frequency factor A is the same for each reaction. Ratio =
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