one atom b) What improvements can be introduced to this function in order to ohtain better bond energy and bond distance.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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b) What improvements can be introduced to this function in order to
obtain better bond energy and bond distance.
wadding Ahoilding
ENO (aflin)intrdueced X facto
c) Which should contribute more to the wave function YA(1) PA(2) or
YB() Y B2)? Explain.
Transcribed Image Text:b) What improvements can be introduced to this function in order to obtain better bond energy and bond distance. wadding Ahoilding ENO (aflin)intrdueced X facto c) Which should contribute more to the wave function YA(1) PA(2) or YB() Y B2)? Explain.
1. a) (Give brief answers)
Consider the molecule Cl-F, assume both atoms to use p orbital.
According to MO theory, the total wave function for the two electrons in
the bonding molecular orbital can be written as:
YaF=Y1). Y b(2) = YA(1).P A(2)+ YA(1). Y B(2)+ YB(1).P B(2)+ PA(2) . Y B(1)
Where YA and YB are the wave functions for the p orbitals of
fluorine atom A and chlorine atom B respectively, and 1 and 2
are the two p electrons
a) Which part or parts of this total waye function represent the covalency
of the molecule? Explain.
cer -thw teる R
be lnen atom
exchange
Which part or parts of this total wave function represent the ionicity of
the molecule? Explain.
ne atom
b) What improvements can be introduced to this function in order to
obtain better bond energy and bond distance.
Transcribed Image Text:1. a) (Give brief answers) Consider the molecule Cl-F, assume both atoms to use p orbital. According to MO theory, the total wave function for the two electrons in the bonding molecular orbital can be written as: YaF=Y1). Y b(2) = YA(1).P A(2)+ YA(1). Y B(2)+ YB(1).P B(2)+ PA(2) . Y B(1) Where YA and YB are the wave functions for the p orbitals of fluorine atom A and chlorine atom B respectively, and 1 and 2 are the two p electrons a) Which part or parts of this total waye function represent the covalency of the molecule? Explain. cer -thw teる R be lnen atom exchange Which part or parts of this total wave function represent the ionicity of the molecule? Explain. ne atom b) What improvements can be introduced to this function in order to obtain better bond energy and bond distance.
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