O₂N- e. f. 1) C 2) H₂NNH₂, NaOH H3O+ .AICI3

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Fill in the missing structure(s) for the reaction pathways shown below.  Provide all starting material(s), reagent(s), or product(s).  If more than one product can be formed, draw all major products.  If more than one starting material is possible, write all starting materials.  Draw all stereoisomers.

The image displays a series of chemical reaction equations labeled as e, f, and g, with structural formulas and reaction conditions.

**e. Reaction Equation**
- **Reactant:** The structure on the left is an aromatic compound with a nitro group (O2N) on the benzene ring, connected via a carbon chain ending in an ester functional group (OCH2CH3).
- **Conditions:** The reaction requires acidic conditions (H3O+).
- **Product:** The product box is empty, indicating that the outcome of the reaction needs to be determined.

**f. Reaction Equation**
- **Reactant:** The structure features a benzene ring with an aldehyde group (CHO) para to a propyl substituent.
- **Conditions:** The reaction proceeds without specified conditions.
- **Product:** The structure of the product shows a benzene ring with a ketone group (C(O)CH2CH3) para to an ethyl group.

**g. Reaction Equation**
- **Reactant:** A hydrocarbon structure with a benzene ring and an alkyl group (isopropyl structure).
- **Conditions:** The reaction involves two steps:
  1. In the presence of chloroform (Cl) and aluminum chloride (AlCl3).
  2. Followed by treatment with hydrazine (H2NNH2) and sodium hydroxide (NaOH).
- **Product:** The product box is left empty, indicating that the final outcome of the reaction pathway is not specified.

Each reaction involves transformations of aromatic compounds under specific chemical conditions, demonstrating typical organic reaction mechanisms.
Transcribed Image Text:The image displays a series of chemical reaction equations labeled as e, f, and g, with structural formulas and reaction conditions. **e. Reaction Equation** - **Reactant:** The structure on the left is an aromatic compound with a nitro group (O2N) on the benzene ring, connected via a carbon chain ending in an ester functional group (OCH2CH3). - **Conditions:** The reaction requires acidic conditions (H3O+). - **Product:** The product box is empty, indicating that the outcome of the reaction needs to be determined. **f. Reaction Equation** - **Reactant:** The structure features a benzene ring with an aldehyde group (CHO) para to a propyl substituent. - **Conditions:** The reaction proceeds without specified conditions. - **Product:** The structure of the product shows a benzene ring with a ketone group (C(O)CH2CH3) para to an ethyl group. **g. Reaction Equation** - **Reactant:** A hydrocarbon structure with a benzene ring and an alkyl group (isopropyl structure). - **Conditions:** The reaction involves two steps: 1. In the presence of chloroform (Cl) and aluminum chloride (AlCl3). 2. Followed by treatment with hydrazine (H2NNH2) and sodium hydroxide (NaOH). - **Product:** The product box is left empty, indicating that the final outcome of the reaction pathway is not specified. Each reaction involves transformations of aromatic compounds under specific chemical conditions, demonstrating typical organic reaction mechanisms.
Expert Solution
Step 1: Predict arrow movement

An arrow always depicts from a region of high electron density to low electron density ; that is tail depicts region of high electron density and head depicts region of low electron density.

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