olid NaF has the so-called NaCl structure. The shortest distance between the centre of a sodium cation and the centre of a fluoride anion is 231.5 pm. Calculate the length of the edge of the conventional face-centred cubic unit cell of NaF. Calculate the density of solid NaF. Calculate the shortest distance (centre to centre) between two fluoride anions in solid NaF.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Solid NaF has the so-called NaCl structure. The shortest distance between the centre of a sodium cation and the centre of a fluoride anion is 231.5 pm.

Calculate the length of the edge of the conventional face-centred cubic unit cell of NaF.

Calculate the density of solid NaF.

Calculate the shortest distance (centre to centre) between two fluoride anions in solid NaF.

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Answer:

Since, NaF has NaCl type structure, therefore In the structure of NaF, fluoride ions will be at the vertices and center of the faces while sodium ions will occupy the octahedral voids formed by fluoride ions.

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