OH KMNO4, hot (f) CH3 H* ČH3 1. NABH4 (g) 2. H20 DIBALH (h) -78 °C

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Give the major organic product(s) for each of the following reactions: 

### Transcription for Educational Website

#### Chemical Reactions

**(f) Reaction**
- **Structure**: A phenyl ring attached to a tertiary alcohol group. The alcohol is bonded to a carbon atom that also has two methyl groups attached.
- **Reagents**: 
  - Potassium permanganate (KMnO4), hot.
  - Acidic condition (H⁺).
- **Description**: This reaction likely involves the oxidation of the alcohol to a ketone or carboxylic acid using hot KMnO4 in the presence of acid.

**(g) Reaction**
- **Structure**: An ester with a propyl group, featuring a ketone group adjacent to an ethyl group.
- **Reagents**: 
  - 1) Sodium borohydride (NaBH4)
  - 2) Water (H2O)
- **Description**: This is a typical ester reduction reaction. The NaBH4 is used to reduce the ester to an alcohol, followed by hydrolysis with water.

**(h) Reaction**
- **Structure**: An ester with a cyclohexyl group attached to a ketone, next to an ethyl group.
- **Reagents**: 
  - Diisobutylaluminum hydride (DIBALH)
- **Conditions**: Temperature maintained at -78°C.
- **Description**: DIBALH is used to selectively reduce the ester to an aldehyde or alcohol at low temperatures, preventing full reduction.
Transcribed Image Text:### Transcription for Educational Website #### Chemical Reactions **(f) Reaction** - **Structure**: A phenyl ring attached to a tertiary alcohol group. The alcohol is bonded to a carbon atom that also has two methyl groups attached. - **Reagents**: - Potassium permanganate (KMnO4), hot. - Acidic condition (H⁺). - **Description**: This reaction likely involves the oxidation of the alcohol to a ketone or carboxylic acid using hot KMnO4 in the presence of acid. **(g) Reaction** - **Structure**: An ester with a propyl group, featuring a ketone group adjacent to an ethyl group. - **Reagents**: - 1) Sodium borohydride (NaBH4) - 2) Water (H2O) - **Description**: This is a typical ester reduction reaction. The NaBH4 is used to reduce the ester to an alcohol, followed by hydrolysis with water. **(h) Reaction** - **Structure**: An ester with a cyclohexyl group attached to a ketone, next to an ethyl group. - **Reagents**: - Diisobutylaluminum hydride (DIBALH) - **Conditions**: Temperature maintained at -78°C. - **Description**: DIBALH is used to selectively reduce the ester to an aldehyde or alcohol at low temperatures, preventing full reduction.
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