OH KMNO4, hot (f) CH3 H* ČH3 1. NABH4 (g) 2. H20 DIBALH (h) -78 °C

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

Give the major organic product(s) for each of the following reactions: 

### Transcription for Educational Website

#### Chemical Reactions

**(f) Reaction**
- **Structure**: A phenyl ring attached to a tertiary alcohol group. The alcohol is bonded to a carbon atom that also has two methyl groups attached.
- **Reagents**: 
  - Potassium permanganate (KMnO4), hot.
  - Acidic condition (H⁺).
- **Description**: This reaction likely involves the oxidation of the alcohol to a ketone or carboxylic acid using hot KMnO4 in the presence of acid.

**(g) Reaction**
- **Structure**: An ester with a propyl group, featuring a ketone group adjacent to an ethyl group.
- **Reagents**: 
  - 1) Sodium borohydride (NaBH4)
  - 2) Water (H2O)
- **Description**: This is a typical ester reduction reaction. The NaBH4 is used to reduce the ester to an alcohol, followed by hydrolysis with water.

**(h) Reaction**
- **Structure**: An ester with a cyclohexyl group attached to a ketone, next to an ethyl group.
- **Reagents**: 
  - Diisobutylaluminum hydride (DIBALH)
- **Conditions**: Temperature maintained at -78°C.
- **Description**: DIBALH is used to selectively reduce the ester to an aldehyde or alcohol at low temperatures, preventing full reduction.
Transcribed Image Text:### Transcription for Educational Website #### Chemical Reactions **(f) Reaction** - **Structure**: A phenyl ring attached to a tertiary alcohol group. The alcohol is bonded to a carbon atom that also has two methyl groups attached. - **Reagents**: - Potassium permanganate (KMnO4), hot. - Acidic condition (H⁺). - **Description**: This reaction likely involves the oxidation of the alcohol to a ketone or carboxylic acid using hot KMnO4 in the presence of acid. **(g) Reaction** - **Structure**: An ester with a propyl group, featuring a ketone group adjacent to an ethyl group. - **Reagents**: - 1) Sodium borohydride (NaBH4) - 2) Water (H2O) - **Description**: This is a typical ester reduction reaction. The NaBH4 is used to reduce the ester to an alcohol, followed by hydrolysis with water. **(h) Reaction** - **Structure**: An ester with a cyclohexyl group attached to a ketone, next to an ethyl group. - **Reagents**: - Diisobutylaluminum hydride (DIBALH) - **Conditions**: Temperature maintained at -78°C. - **Description**: DIBALH is used to selectively reduce the ester to an aldehyde or alcohol at low temperatures, preventing full reduction.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 2 images

Blurred answer
Knowledge Booster
Thermochemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY