O KINETICS AND EQUILIBRIUM Using an equilibrium constant to predict the direction of spontaneous reaction A chemical engineer is studying the following reaction: H,(9)+Cl,(9) → 2 HC1(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.72. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the compe mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel H, 5.79 atm I decrease (no change) increase C1, 4.17 atm ↑ increase I decrease (no change) нсі 4.17 atm f increase I decrease (no change) H, 4.63 atm f increase decrease (no change) Cl, 3.43 atm I decrease (no change) increase 2.40 atm O (no change) нсі ↑ increase Į decrease H, 4.66 atm decrease (no change) increase C1, 3.46 atm ↑ increase I decrease O (no change) HCI 2.34 atm f increase I decrease (no change)
O KINETICS AND EQUILIBRIUM Using an equilibrium constant to predict the direction of spontaneous reaction A chemical engineer is studying the following reaction: H,(9)+Cl,(9) → 2 HC1(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.72. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the compe mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel H, 5.79 atm I decrease (no change) increase C1, 4.17 atm ↑ increase I decrease (no change) нсі 4.17 atm f increase I decrease (no change) H, 4.63 atm f increase decrease (no change) Cl, 3.43 atm I decrease (no change) increase 2.40 atm O (no change) нсі ↑ increase Į decrease H, 4.66 atm decrease (no change) increase C1, 3.46 atm ↑ increase I decrease O (no change) HCI 2.34 atm f increase I decrease (no change)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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