O KINETICS AND EQUILIBRIUM Using an equilibrium constant to predict the direction of spontaneous reaction A chemical engineer is studying the following reaction: H,(9)+Cl,(9) → 2 HC1(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.72. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the compe mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel H, 5.79 atm I decrease (no change) increase C1, 4.17 atm ↑ increase I decrease (no change) нсі 4.17 atm f increase I decrease (no change) H, 4.63 atm f increase decrease (no change) Cl, 3.43 atm I decrease (no change) increase 2.40 atm O (no change) нсі ↑ increase Į decrease H, 4.66 atm decrease (no change) increase C1, 3.46 atm ↑ increase I decrease O (no change) HCI 2.34 atm f increase I decrease (no change)

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O KINETICS AND EQUILIBRIUM
Using an equilibrium constant to predict the direction of spontaneous reaction
A chemical engineer is studying the following reaction:
H,(9)+Cl,(9) → 2 HC1(g)
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.72.
The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the compe
mixture inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
compound
pressure
expected change in pressure
vessel
H,
5.79 atm
I decrease
(no change)
increase
C1,
4.17 atm
↑ increase
I decrease
(no change)
нсі
4.17 atm
f increase
I decrease
(no change)
H,
4.63 atm
f increase
decrease
(no change)
Cl,
3.43 atm
I decrease
(no change)
increase
2.40 atm
O (no change)
нсі
↑ increase
Į decrease
H,
4.66 atm
decrease
(no change)
increase
C1,
3.46 atm
↑ increase
I decrease
O (no change)
HCI
2.34 atm
f increase
I decrease
(no change)
Transcribed Image Text:O KINETICS AND EQUILIBRIUM Using an equilibrium constant to predict the direction of spontaneous reaction A chemical engineer is studying the following reaction: H,(9)+Cl,(9) → 2 HC1(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.72. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the compe mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel H, 5.79 atm I decrease (no change) increase C1, 4.17 atm ↑ increase I decrease (no change) нсі 4.17 atm f increase I decrease (no change) H, 4.63 atm f increase decrease (no change) Cl, 3.43 atm I decrease (no change) increase 2.40 atm O (no change) нсі ↑ increase Į decrease H, 4.66 atm decrease (no change) increase C1, 3.46 atm ↑ increase I decrease O (no change) HCI 2.34 atm f increase I decrease (no change)
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