Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Exercise Instructions:**
1. **Objective**: Draw the tautomer of the given aldehyde. Make sure to include all lone pairs in your drawing. You should ignore inorganic byproducts in this process.
2. **Chemical Structure Provided**:
- The chemical structure showcases an aldehyde with a benzene ring (phenyl group) attached to a propanal group (three-carbon chain ending with an aldehyde functional group).
3. **Reaction Condition**:
- The conversion is to be performed in the presence of H₃O⁺ (hydronium ion), which acts as a catalyst for the tautomerization reaction.
4. **Response to Input**:
- The initial attempt has been marked incorrect, with a reminder that 2 attempts remain.
5. **Diagram Details**:
- **Initial Structure**: The image depicts the aldehyde with lone pairs on the oxygen atom.
- **Attempted Tautomer Structure**: The drawing reflects an incorrect enol form, where an -OH group is attached to a carbon that was originally near the double-bonded oxygen.
6. **Instruction Visuals**:
- The visual representation includes a large arrow indicating the transformation process from the aldehyde to the enol form.
- An error indication is shown in the form of a red cross suggesting the attempted tautomer formation is incorrect.
**Guidance for Attempts**:
- Reevaluate the placement of hydrogen and hydroxyl groups.
- Ensure the enol form respects the proper keto-enol tautomerization mechanism, focusing on the proton shift and formation of a new double bond adjacent to the hydroxyl group.
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