nucleophile: e-donor electrophile: E acceptor Q. No. IV). organometallics are always nucleophiles Predict the products for each of the following reactions. Indicate a rational mechanism in each case. Label each reactant as a nucleophile or an electrophile. 5. 1. 2. (CH3)3 COH + (CH3)3CMaBr (CH3)3c0mgBr Mechanism: + (CH3)3c0JH + (CH3)3c-mg B (CH3)3 CH Mechanism: CHO 3. CH,C CH + + H CH3MgBr NaN H2 + Mechanism: CH3 C = GJ H Li Mechanism: BF3 Mechanism: L-A CO2 + CH3Jmg Br omgBr Ç-H сна CH3C=C-Na + NGÀNH, NH3T ༠༠; CH3 CH3OCH3

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nucleophile: e-donor
electrophile: E acceptor
Q. No. IV).
organometallics
are always
nucleophiles
Predict the products for each of the following reactions. Indicate a rational mechanism
in each case. Label each reactant as a nucleophile or an electrophile.
5.
1.
2.
(CH3)3 COH
+
(CH3)3CMaBr
(CH3)3c0mgBr
Mechanism:
+
(CH3)3c0JH
+
(CH3)3c-mg B
(CH3)3 CH
Mechanism:
CHO
3.
CH,C CH
+
+
H
CH3MgBr
NaN H2
+
Mechanism:
CH3 C = GJ H
Li
Mechanism:
BF3
Mechanism:
L-A
CO2
+
CH3Jmg Br
omgBr
Ç-H
сна
CH3C=C-Na
+
NGÀNH,
NH3T
༠༠;
CH3
CH3OCH3
<H3
十
L.
CH3
។
F3B.
·CH3
* nucleophiles
attack positive end
of polar bonds
Determine by polarity
Transcribed Image Text:nucleophile: e-donor electrophile: E acceptor Q. No. IV). organometallics are always nucleophiles Predict the products for each of the following reactions. Indicate a rational mechanism in each case. Label each reactant as a nucleophile or an electrophile. 5. 1. 2. (CH3)3 COH + (CH3)3CMaBr (CH3)3c0mgBr Mechanism: + (CH3)3c0JH + (CH3)3c-mg B (CH3)3 CH Mechanism: CHO 3. CH,C CH + + H CH3MgBr NaN H2 + Mechanism: CH3 C = GJ H Li Mechanism: BF3 Mechanism: L-A CO2 + CH3Jmg Br omgBr Ç-H сна CH3C=C-Na + NGÀNH, NH3T ༠༠; CH3 CH3OCH3 <H3 十 L. CH3 ។ F3B. ·CH3 * nucleophiles attack positive end of polar bonds Determine by polarity
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