Answered: НС ҫH2 Он НС CH2 CH2 Ketone…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

A reaction for converting ketones to lactones, called the
Baeyer–Villiger reaction,

is used in the manufacture of plastics and pharmaceuticals.
3-Chloroperbenzoic acid is shock-sensitive, however,
and prone to explode. Also, 3-chlorobenzoic acid is
a waste product. An alternative process being developed
uses hydrogen peroxide and a catalyst consisting of tin
deposited within a solid support. The catalyst is readily
recovered from the reaction mixture. (a) What would
you expect to be the other product of oxidation of the
ketone to lactone by hydrogen peroxide? (b) What principles
of green chemistry are addressed by use of the proposed
process?

НС
ҫH2
Он
НС
CH2
CH2
Ketone
3-Chloroperbenzoic acid
НС
ОН
НС,
CH2
H,C-CH2
Lactone
3-Chlorobenzoic acid

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

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