Noting the curved arrows, draw all the product(s), organic and inorganic, of the following reaction. H3C CH3 • You do not have to consider stereochemistry. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu.
Basics in Organic Reactions Mechanisms
In organic chemistry, the mechanism of an organic reaction is defined as a complete step-by-step explanation of how a reaction of organic compounds happens. A completely detailed mechanism would relate the first structure of the reactants with the last structure of the products and would represent changes in structure and energy all through the reaction step.
Heterolytic Bond Breaking
Heterolytic bond breaking is also known as heterolysis or heterolytic fission or ionic fission. It is defined as breaking of a covalent bond between two different atoms in which one atom gains both of the shared pair of electrons. The atom that gains both electrons is more electronegative than the other atom in covalent bond. The energy needed for heterolytic fission is called as heterolytic bond dissociation energy.
Polar Aprotic Solvent
Solvents that are chemically polar in nature and are not capable of hydrogen bonding (implying that a hydrogen atom directly linked with an electronegative atom is not found) are referred to as polar aprotic solvents. Some commonly used polar aprotic solvents are acetone, DMF, acetonitrile, DMSO, etc.
Oxygen Nucleophiles
Oxygen being an electron rich species with a lone pair electron, can act as a good nucleophile. Typically, oxygen nucleophiles can be found in these compounds- water, hydroxides and alcohols.
Carbon Nucleophiles
We are aware that carbon belongs to group IV and hence does not possess any lone pair of electrons. Implying that neutral carbon is not a nucleophile then how is carbon going to be nucleophilic? The answer to this is that when a carbon atom is attached to a metal (can be seen in the case of organometallic compounds), the metal atom develops a partial positive charge and carbon develops a partial negative charge, hence making carbon nucleophilic.
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**Task Requirements:**
- You do not have to consider stereochemistry.
- Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
- Separate structures with "+" signs from the drop-down menu.
**Reaction Mechanism Detail:**
1. The curved arrow indicates the electron movement.
2. The reaction involves a nucleophilic attack where the electrons from the pi bond of propene (CH₃CH=CH₂) attack a proton (H⁺), leading to the formation of a new bond.
**Diagram Explanation:**
The top section shows a chemical reaction mechanism:
- **Reactants:** A propene molecule and a hydrogen cation (H⁺).
- **Curved Arrow:** Indicates the movement of electrons from the double bond in propene towards the H⁺ ion.
The tool shown is a ChemDoodle interface for drawing chemical structures.
Please use the tools provided in the interface to accurately depict the chemical structures that result from the reaction described above.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2490d18d-134b-4915-8be9-67f42ad3cb55%2Fb72fecb8-8c73-4be3-9714-32967f4805e0%2Fitj31w_processed.png&w=3840&q=75)
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