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NO2 AICI3 CH3-C-CI NO2 NO2 NO2 ċ-CH3 None of these ċ-CH3 III IV II C-CH3 (a) I only (b) II only (c) III only (d) IV only (e) I and III only +

NO2 AICI3 CH3-C-CI NO2 NO2 NO2 ċ-CH3 None of these ċ-CH3 III IV II C-CH3 (a) I only (b) II only (c) III only (d) IV only (e) I and III only +

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What is (are) the product(s) of the following reaction?
**Aromatic Substitution Reaction: Friedel-Crafts Acylation** In the image provided, a chemical reaction is depicted which illustrates the Friedel-Crafts acylation, a common type of electrophilic aromatic substitution. The reaction involves the introduction of an acyl group into an aromatic ring. ### Reactants: 1. **Nitrobenzene**: A benzene ring with a nitro group (NO\(_2\)) attached. 2. **Acetyl Chloride (CH\(_3\)COCl)**: A common acylating agent. ### Catalyst: - **Aluminum Chloride (AlCl\(_3\))**: Used to facilitate the Friedel-Crafts acylation. ### Reaction Arrow: - An arrow indicating the direction of the reaction from reactants to products. ### Products: In this reaction, the nitrobenzene undergoes acylation, producing one or more of the potential products depicted below: 1. **Product I**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the para position. 2. **Product II**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the meta position. 3. **Product III**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the ortho position. 4. **Product IV**: A benzene ring with an acyl group (COCH\(_3\)) in an incorrect structural position relative to the nitro group. ### Response Options: The chemical reaction is followed by multiple-choice options (a-e) to determine the correct product(s): - **(a) I only** - **(b) II only** - **(c) III only** - **(d) IV only** - **(e) I and III only** ### Detailed Analysis: Based on the electrophilic aromatic substitution mechanism, the nitro group is a meta-directing group due to its electron-withdrawing nature. Hence, the acylation will predominantly occur at the meta position relative to the nitro group. ### Conclusion: The correct product(s) can be concluded considering the directing effects and the resulting positions of the substituents on the benz
Transcribed Image Text:**Aromatic Substitution Reaction: Friedel-Crafts Acylation** In the image provided, a chemical reaction is depicted which illustrates the Friedel-Crafts acylation, a common type of electrophilic aromatic substitution. The reaction involves the introduction of an acyl group into an aromatic ring. ### Reactants: 1. **Nitrobenzene**: A benzene ring with a nitro group (NO\(_2\)) attached. 2. **Acetyl Chloride (CH\(_3\)COCl)**: A common acylating agent. ### Catalyst: - **Aluminum Chloride (AlCl\(_3\))**: Used to facilitate the Friedel-Crafts acylation. ### Reaction Arrow: - An arrow indicating the direction of the reaction from reactants to products. ### Products: In this reaction, the nitrobenzene undergoes acylation, producing one or more of the potential products depicted below: 1. **Product I**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the para position. 2. **Product II**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the meta position. 3. **Product III**: A benzene ring with an acyl group (COCH\(_3\)) and a nitro group (NO\(_2\)) in the ortho position. 4. **Product IV**: A benzene ring with an acyl group (COCH\(_3\)) in an incorrect structural position relative to the nitro group. ### Response Options: The chemical reaction is followed by multiple-choice options (a-e) to determine the correct product(s): - **(a) I only** - **(b) II only** - **(c) III only** - **(d) IV only** - **(e) I and III only** ### Detailed Analysis: Based on the electrophilic aromatic substitution mechanism, the nitro group is a meta-directing group due to its electron-withdrawing nature. Hence, the acylation will predominantly occur at the meta position relative to the nitro group. ### Conclusion: The correct product(s) can be concluded considering the directing effects and the resulting positions of the substituents on the benz
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